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30421. 题目: Facile low-temperature one-step synthesis of pomelo peel biochar under air atmosphere and its adsorption behaviors for Ag(I) and Pb(II)
文章编号: N18053104
期刊: Science of The Total Environment
作者: Tuo Zhao, Ying Yao, Danrong Li, Feng Wu, Cunzhong Zhang, Bin Gao
更新时间: 2018-05-31
摘要: This study prepared a novel low-cost surface functionalized carbon adsorbent (PPC) from biomass waste (pomelo peel) through a facile low-temperature (250 °C) one-step method under regular air atmosphere. The adsorption performance and mechanism of the carbon material for Ag(I) and Pb(II) were investigated by a range of sorption experiments and characterizations including SEM, EDX, XRD and FTIR. Sorption experimental results suggested that PPC had high adsorption capacities of 137.4 and 88.7 mg/g for Ag(I) and Pb(II), respectively, with adsorbent dosage of 2 g/L at unadjusted solution pH and room temperature (23 ± 1 °C). The characterization results indicated high-efficiency removal of the heavy metals by PPC was attributed to the strong chemical adsorption involving that Ag(I) ions were reduced as metallic Ag particles by oxygenic functional groups and Pb(II) ions were precipitated as Pb5(PO4)3OH crystals by phosphorous functional groups on the carbon surfaces. This study provides the possibility of synthesis high-efficient adsorbent using economic and environmental-friendly approach with low energy consumption.
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30422. 题目: Monocarboxylic and dicarboxylic acids over oceans from the East China Sea to the Arctic Ocean: Roles of ocean emissions, continental input and secondary formation
文章编号: N18053103
期刊: Science of The Total Environment
作者: Qihou Hu, Zhouqing Xie, Xinming Wang, Hui Kang, Yuqing Zhang, Xiang Ding, Pengfei Zhang
更新时间: 2018-05-31
摘要: Organic acids are major components in marine organic aerosols. Many studies on the occurrence, sources and sinks of organic acids over oceans in the low and middle latitudes have been conducted. However, the understanding of relative contributions of specific sources to organic acids over oceans, especially in the high latitudes, is still inadequate. This study measured organic acids, including C14:0 – C32:0 saturated monocarboxylic acids (MCAs), C16:1, C18:1 and C18:2 unsaturated MCAs, and di-C4 – di-C10 dicarboxylic acids (DCAs), in the marine boundary layer from the East China Sea to the Arctic Ocean during the 3rd Chinese Arctic Research Expedition (CHINARE 08). The average concentrations were 18 ± 16 ng/m3 and 11 ± 5.4 ng/m3 for ΣMCA and ΣDCA, respectively. The levels of saturated MCAs were much higher than those of unsaturated DCAs, with peaks at C16:0, C18:0 and C14:0. DCAs peaked at di-C4, followed by di-C9 and di-C8. Concentrations of MCAs and DCAs generally decreased with increasing latitudes. Sources of MCAs and DCAs were further investigated using principal component analysis with a multiple linear regression (PCA-MLR) model. Overall, carboxylic acids originated from ocean emissions, continental input (including biomass burning, anthropogenic emissions and terrestrial plant emissions), and secondary formation. All the five sources contributed to MCAs with ocean emissions as the predominant source (48%), followed by biomass burning (20%). In contrast, only 3 sources (i.e., secondary formation (50%), anthropogenic emissions (41%) and biomass burning (9%)) contributed to DCAs. Furthermore, the sources varied with regions. Over the Arctic Ocean, only secondary formation and anthropogenic emissions contributed to MCAs and DCAs.
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30423. 题目: Retention and characteristics of microplastics in natural zooplankton taxa from the East China Sea
文章编号: N18053102
期刊: Science of The Total Environment
作者: Xiaoxia Sun, Tao Liu, Mingliang Zhu, Junhua Liang, Yongfang Zhao, Bo Zhang
更新时间: 2018-05-31
摘要: The ubiquitous presence and persistence of microplastics (MPs) in aquatic environments have become of particular concern in recent years. Biological interactions are among the key processes that affect the impact and fate of MPs in the oceans. Zooplankton is one of the most sensitive taxa because their prey is approximately the same size as MPs. However, the status of MPs in zooplankton within natural marine environments remains largely unknown. By focusing on zooplankton in the East China Sea, the characteristics, bioaccumulated concentration, and retention of MPs for 10 zooplankton groups were systematically studied. Three types of MPs were found in zooplankton: fibres, pellets, and fragments. The fibres (54.6%) were more common than the other two types. The average lengths of the fibres, pellets, and fragments were 295.2 ± 348.6 μm, 20.3 ± 11.0 μm, and 82.4 ± 80.5 μm, respectively. Nineteen polymers were detected in the zooplankton via the Thermo Scientific Nicolet iN10 Infrared Microscope. Polymerized oxidized organic material and polyester were dominant, accounting for 35.9% and 25.6% of the polymers, respectively. The bioaccumulated concentration of MPs in the 10 zooplankton taxa varied from 0.13 pieces/zooplankton for Copepoda to 0.35 pieces/zooplankton for Pteropoda. The bioaccumulated concentration was negatively correlated with the abundance of zooplankton, showing a significant biological dilution effect. The bioaccumulated concentration was also influenced by the feeding mode of zooplankton, showing a trend of omnivorous > carnivorous > herbivorous. High retention of MPs was found in the zooplankton community of the East China Sea, achieving 19.7 ± 22.4 pieces/m3. This is much higher than the MP retention in zooplankton from other reported sea areas. By revealing the characteristics and retention of MPs in the natural zooplankton taxa from the East China Sea, this research identified the influence that MPs have on zooplankton in a typical coastal environment. This information can be utilized for subsequent controlled experiments and risk assessments.
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30424. 题目: Using fluorescence-parallel factor analysis for assessing disinfection by-product formation and natural organic matter removal efficiency in secondary treated synthetic drinking waters
文章编号: N18053101
期刊: Science of The Total Environment
作者: Kalinda Watson, Maria José Farré, Frederic D.L. Leusch, Nicole Knight
更新时间: 2018-05-31
摘要: Parallel factor (PARAFAC) analysis of fluorescence excitation-emission matrices (EEMs) was used to investigate the organic matter and DBP formation characteristics of untreated, primary treated (enhanced coagulation; EC) and secondary treated synthetic waters prepared using a Suwannee River natural organic matter (SR-NOM) isolate. The organic matter was characterised by four different fluorescence components; two humic acid-like (C1 and C2) and two protein-like (C3 and C4). Secondary treatment methods tested, following EC treatment, were; powdered activated carbon (PAC), granular activated carbon (GAC), 0.1% silver-impregnated activated carbon (SIAC), and MIEX resin. Secondary treatments were more effective at removing natural organic matter (NOM) and fluorescent DBP-precursor components than EC alone. The formation of a suite of 17 DBPs including chlorinated, brominated and iodinated trihalomethanes (THMs), dihaloacetonitriles (DHANs), chloropropanones (CPs), chloral hydrate (CH) and trichloronitromethane (TCNM) was determined after chlorinating water sampled before and after each treatment step. Regression analysis was used to investigate the relationship between peak component fluorescence intensity (FMAX), DBP concentration and speciation, and more commonly used aggregate parameters such as DOC, UV254 and SUVA254. PARAFAC component 1 (C1) was in general a better predictor of DBP formation than other aggregate parameters, and was well correlated (R ≥ 0.80) with all detected DBPs except dibromochloromethane (DBCM) and dibromoacetonitrile (DBAN). These results indicate that the fluorescence-PARAFAC approach could provide a robust analytical tool for predicting DBP formation, and for evaluating the removal of NOM fractions relevant to DBP formation during water treatment.
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30425. 题目: Characteristics and compound-specific carbon isotope compositions of sedimentary lipids in high arsenic aquifers in the Hetao basin, Inner Mongolia
文章编号: N18052929
期刊: Environmental Pollution
作者: Ruoyu Mao, Huaming Guo, Wei Xiu, Yuance Yang, Xianyu Huang, Yinzhu Zhou, Xiaomeng Li, Jianyi Jin
更新时间: 2018-05-29
摘要: Organic matter, as an electron donor, plays a vital role in As mobilization mediated by microorganisms during reductive dissolution of Fe/Mn oxides in shallow aquifers. However, the specific types and sources of organic matter involved in biogeochemical processes accelerating As mobilization are still controversial. Both sediment and groundwater samples were collected at different depths from aquifers of the Hetao Basin, a typical inland basin hosting high As groundwater. Sedimentary lipids and their compound-specific carbon isotope ratios were analyzed to evaluate characteristics and sources of organic matter. Results show that sedimentary As were well correlated with Fe and Mn oxides, suggesting that As exist as Fe/Mn oxide bound forms. Groundwater As far exceeded the drinking water guide value of 10 μg/L. Moreover, As concentrations in shallow groundwater were relatively higher. Lipids in clay were mainly originated from terrestrial higher plants, while that in fine sand samples were derived from terrestrial higher plants, microorganism and petroleum. Shallow fine sand samples were also characterized by evident in-situ biodegradation. Compound-specific carbon isotope compositions of sedimentary lipids showed that short-chain n-alkanes and n-alkanoic acids had more positive δ13C values compared to long-chain compounds, especially in shallow fine sand samples. δ13CTOC were also low in shallow fine sand samples. These results jointly indicate that these lipids in shallow fine sand samples acted as carbon source for indigenous microorganism and the short-chain components were particularly more vulnerable to biodegradation, which may contribute to high As concentrations in shallow groundwater. The new findings provide the first evidence that short chain length n-alkyl compounds afforded a source of potential electron donors for microbially mediated As mobilization process in the shallow aquifers.
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30426. 题目: Comparing macroinvertebrate assemblages at organic-contaminated river sites with different zinc concentrations: Metal-sensitive taxa may already be absent
文章编号: N18052928
期刊: Environmental Pollution
作者: Yuichi Iwasaki, Takashi Kagaya, Hiroyuki Matsuda
更新时间: 2018-05-29
摘要: We investigated responses of macroinvertebrates to different zinc concentrations in urban rivers contaminated with organic matter in a regional-scale monitoring survey and a smaller-scale field study. The present study was designed to test our prediction that total zinc concentrations of 60 μg/L (twice the Japanese environmental quality standard) do not lead to significant reductions in richness or abundance of macroinvertebrates in organic-contaminated rivers (biochemical oxygen demand of >3 mg/L). At the organic-contaminated sites in both surveys, very few species were present, and metal-sensitive heptageniid and ephemerellid mayflies were generally absent. In the regional-scale study, total zinc concentrations of up to 70 μg/L resulted in little reduction in macroinvertebrate richness. In the local-scale study, macroinvertebrate richness and abundance were not greatly reduced at the polluted downstream site with a total zinc concentration of 48 μg/L. Results from both surveys support our prediction. Therefore, an important implication of this study is that macroinvertebrate taxa that are susceptible to metal pollution should be sparse or absent in organic-contaminated rivers, so the impacts of metals such as zinc may be limited owing to the species-poor communities. Further research is required to evaluate the importance of reduced zinc bioavailability associated with increased organic matter and water hardness to the species-poor communities in organic-contaminated rivers.
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30427. 题目: Interactions between iron mineral-humic complexes and hexavalent chromium and the corresponding bio-effects
文章编号: N18052927
期刊: Environmental Pollution
作者: Zhiyong Zheng, Yue Zheng, Xiaochun Tian, Zhaohui Yang, Yanxia Jiang, Feng Zhao
更新时间: 2018-05-29
摘要: The interfacial behaviors of chromium are fundamental for understanding the environmental effects of chromium in contaminated environments. However, complex surfaces can cause chromium to exhibit a variety of behaviors, especially when humic substances are considered. This work illustrated the role of humics (humic acid and fulvic acid) during the adsorption of Cr(VI) onto iron minerals (magnetite and hematite). The interfacial behaviors were investigated through their adsorption kinetics, adsorption isotherms, and thermodynamics. Then, the microbial diversity was monitored to reflect the bio-effects of Cr(VI) adsorbed onto four iron oxide-humic complexes. The differences in the adsorption capacities and mechanisms of Cr(VI) on the surfaces of the iron mineral-humic complexes were observed. Humics obviously decreased the adsorption capacities of Cr(VI) on the hematite complexes and relieved the decline in the microbial diversity; meanwhile, humics imposed relatively insignificant changes to the Cr(VI) adsorption capacity onto the magnetite complexes. Thus, the corresponding microbial diversity might be mainly affected by released micelles formed by Cr(VI) and humics. These results illustrate the complexities of the interfacial behaviors of Cr(VI) on the surfaces of iron mineral-humic complexes and broaden the current understanding of chromium migration and transportation.
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30428. 题目: Exogenous acyl-homoserine lactones adjust community structures of bacteria and methanogens to ameliorate the performance of anaerobic granular sludge
文章编号: N18052926
期刊: Journal of Hazardous Materials
作者: Longyi Lv, Weiguang Li, Zejia Zheng, Donghui Li, Ning Zhang
更新时间: 2018-05-29
摘要: Quorum sensing (QS) signalling has been extensively studied in single species populations, activated sludge, biofilm and aerobic granular sludge. However, ecological roles of QS in anaerobic granular sludge, particularly in the content of the relationship between QS signalling and microbial community composition and function, have been rarely reported. Herein, five acyl-homoserine lactones (AHLs) molecules were added in the anaerobic granular sludge system for treating traditional Chinese medicine (TCM) wastewater respectively. The results indicated that the introduction of specific AHLs could enhance the abilities of organic matters removal and methanation in anaerobic granular sludge, and meanwhile, exogenous AHLs played an important role to regulate the concentration of EPS. Sequencing analysis indicated that microbial community structures of bacteria and methanogens changed to varying degrees by adding AHLs. This study suggested that exogenous AHLs could play a role in mediating microbial community structure, thereby enhancing the performance of anaerobic granular sludge. The regulatory mechanism of AHLs on community structure was discussed, and a speculative action model was established. Exogenous regulation by selective enhancement of AHLs-mediated QS in anaerobic granular sludge provided an innovative and attractive strategy for strengthening wastewater treatments.

30429. 题目: Exploring the fate and oxidation behaviors of different organic constituents in landfill leachate upon Fenton oxidation processes using EEM-PARAFAC and 2D-COS-FTIR
文章编号: N18052925
期刊: Journal of Hazardous Materials
作者: Bilal Aftab, Hyun-Sang Shin, Jin Hur
更新时间: 2018-05-29
摘要: In this work, the changes of different organic constituents in landfill leachate were tracked in Fenton oxidation processes with different operation parameters including H2O2 doses, pH, and the ratios of [H2O2]/[Fe] via fluorescence excitation emission matrix – parallel factor analysis (EEM-PARAFAC) and two-dimensional correlation spectroscopy (2D-COS). One tryptophan-like (C1), one fulvic-like (C2), and one humic-like (C3) components were identified in the leachates. The removal behaviors of the individual fluorescent components were dependent upon the operation conditions, suggesting the existence of unique characteristics with respect to the responses to the oxidation mechanisms, which were likely altered by different operation conditions. For all tested conditions, a greater extent of removal was consistently found for C3 versus C1 and C2 except for the relatively high pH ranges (>6.0), in which C2 presented the highest removal rates. 2D-COS combined with synchronous fluorescence spectra exhibited the preferential oxidation sequence in the order of C3 > C1 > C2 with higher H2O2 doses. 2D-COS coupled with Fourier transform infrared (2D-COS-FTIR) showed that aromatic functional groups were initially oxidized, followed by the removal of carboxylic groups and the formation of inorganic functional groups and aldehyde or ketonic groups. Hetero 2D-COS maps further revealed the close association between the aromatic groups and C3, and between the carboxylic groups and C1. This study utilizing 2D-COS provided new insights into the dynamic behavior of heterogeneous landfill leachate in Fenton oxidation processes under varying operation conditions.
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30430. 题目: Influence of natural organic matter on horseradish peroxidase-mediated removal of 17α-ethinylestradiol: Role of molecular weight
文章编号: N18052924
期刊: Journal of Hazardous Materials
作者: Yun Yang, Jianhua Li, Huanhuan Shi, Li Zhai, Xing Wang, Shixiang Gao
更新时间: 2018-05-29
摘要: Ubiquitous natural organic matter (NOM) plays a crucial role in the peroxidase-mediated transformation of phenolic pollutants in aquatic environment. As a poorly defined polydispersed mixture of assorted organic substances with wide molecular weight (MW) distribution, NOM has far prevented researchers from finding out the primarily responsible components for the specific effect. In this work, MW fractionated NOMs (Mf-NOMs) were used to investigate their roles on horseradish peroxidase (HRP)-mediated transformation of 17α-ethinylestradiol (EE2). The removal rate of EE2 was restrained in the presence of pristine or Mf-NOMs, and the inhibitory mechanism was MW-dependent. Low Mf-NOMs restrained the enzymatic reaction by acting as competitive substrates, while high Mf-NOMs retained freely dissolved EE2 which reduced its availability for enzymatic reaction. The contribution of these two processes to the inhibition induced by pristine NOM was further quantified and found to be relevant to the reaction conditions, especially EE2 concentration. The findings of this work reveal more complex influences of NOM on the enzymatic reaction than ever demonstrated, which aids in understanding the fate of EE2 and other congener contaminants in natural and municipal water.
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30431. 题目: Raw hematite based Fe(III) bio-reduction process for humified landfill leachate treatment
文章编号: N18052923
期刊: Journal of Hazardous Materials
作者: Rui Li, Yu Jiang, Beidou Xi, Mingxiao Li, Xiaoguang Meng, Chuanping Feng, Xuhui Mao, Hongliang Liu, Yonghai Jiang
更新时间: 2018-05-29
摘要: Microorganisms from paddy soils and raw hematite are used for enhancing natural Fe(III) bio-reduction, in order to remove macromolecular organic pollutants from humified landfill leachate. Based on batch experiments, 60% of refractory organics can be adsorbed by hematite in 12 days. In the presence of Fe(III)-reducing bacteria, 489.60 ± 0.14 mg L-1 of dissolved organic matters can be degraded to 51.90 ± 3.96 mg L-1 within 50 days; twelve types of semi volatile organic compounds can be degraded; hereby, the reaction follows a first-order kinetics. Crystalline Fe(III) is transformed into the amorphous form and reduced to Fe(II), hydroquinone functional groups in the humic acid (HA) are transformed to quinone ones, and the formation of HA-hematite ligands is promoted. Comparing with most of the studies about electron shuttling of HA, the transformation of quinone in the HA to hydroquinone could not be observed in the present bio-system. Based on column evaluations, more than 93% of chemical oxygen demand (influent concentration of 658 ± 19 mg L-1) could be removed microbially under flow conditions, when the hydraulic retention time was 45 h. Raw hematite-based Fe(III) bio-reduction has a promising potential for the removal of humic and benzene series in humified landfill leachate.
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30432. 题目: Functional lignocellulosic material for the remediation of copper(II) ions from water: Towards the design of a wood filter
文章编号: N18052922
期刊: Journal of Hazardous Materials
作者: Selin Vitas, Tobias Keplinger, Nico Reichholf, Renato Figi, Etienne Cabane
更新时间: 2018-05-29
摘要: In this study, the chemical modification of bulk beech wood is described along with its utilization as biosorbent for the remediation of copper from water. The material was prepared by esterification using anhydrides, and reaction conditions were optimized to propose a greener process, in particular by reducing the amount of solvent. This modification yields a lignocellulosic material whose native structure is preserved, with an increased amount of carboxylic groups (up to 3 mmol/g). We demonstrate that the material can remove up to 95% of copper from low concentration solutions (100– 500 ppm). The adsorption efficiency decreases with concentrated copper solutions, and we show that a limited number of -COOH groups participate in copper binding (ca. 0.1 Cu/-COOH). This result suggests a limited accessibility of -COOH groups in the wood scaffold. This was demonstrated by the characterization of -COOH and copper distributions inside wood. Raman and EDX imaging confirmed that most –COOH groups are located inside the wood cell walls, thereby limiting interactions with copper. According to this study, critical limitations of bulk wood as a biosorbent were identified, and the results will be used to improve the material and design an efficient wood filter for heavy metal remediation.
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30433. 题目: Binding of Cd by ferrihydrite organo-mineral composites: Implications for Cd mobility and fate in natural and contaminated environments
文章编号: N18052921
期刊: Chemosphere
作者: Huihui Du, Caroline L. Peacock, Wenli Chen, Qiaoyun Huang
更新时间: 2018-05-29
摘要: Adsorption and coprecipitation of organic matter with iron (hydr)oxides can alter iron (hydr)oxide surface properties and their reactivity towards nutrient elements and heavy metals. Organo-mineral composites were synthesized using humic acid (HA) and iron oxide, during coprecipitation with ferrihydrite (Fh) and adsorption to pre-formed Fh with two C loadings. The Fh-HA coprecipitated composites have a higher C content and smaller surface area compared to the equivalent adsorbed composites. NanoSIMS shows there is a high degree of spatial correlation between Fe and C for both composites, but C distribution is more uniform in the coprecipitated composites. The C 1s NEXAFS reveals a similar C composition between the Fh-HA coprecipitated and adsorbed composites. However composites at high carbon loading are more enriched in aromatic C, likely due to preferential binding of carboxyl functional groups on aromatic rings in the HA. The amount of Cd sorbed is independent of the composite type, either coprecipitated or adsorbed, but is a function of the C loading. Composites with low C loading show Cd sorption that is almost identical to pure Fh, while composites with high C loading show Cd sorption that is intermediate between pure Fh and pure HA, with sorption significantly enhanced over pure Fh at pH < 6.5. A bidentate edge-sharing binding was identified for Cd on pure Fh and Cd-carboxyl binding on pure HA. These findings have significant implications not only for the sequestration of Cd in contaminated environments but also the coupled biogeochemical cycling of Cd, Fe and C in the critical zone.
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30434. 题目: Effects of chemical oxidation on surface oxygen-containing functional groups and adsorption behavior of biochar
文章编号: N18052920
期刊: Chemosphere
作者: Qinya Fan, Jianxiong Sun, Lei Chu, Liqiang Cui, Guixiang Quan, Jinlong Yan, Qaiser Hussain, Muhammad Iqbal
更新时间: 2018-05-29
摘要: Biochar is a beneficial soil amendment but the changes in its surface properties during the aging process, especially the oxygen-containing functional groups and the associated adsorption behaviors, are not well documented. In this paper, the aged wheat straw biochar was simulated by chemical oxidation with HNO3-H2SO4 and NaOH-H2O2 systems. Characterization results showed that carbon loss and oxygen incorporation ran throughout the aging process. Surface oxygen-containing functional groups were found to be increased in all treated biochars, especially for carboxyl. Much more developed mesopores were observed in aging biochar, specific surface area was increased by 126% for biochar treated with NaOH-H2O2, and 226% for biochar treated with 40% of HNO3-H2SO4. Thermogravimetric analysis showed that the increasing oxygen-containing functional groups led to 14% and 30% mass loss by treating biochar with alkali and acid, respectively. The improved biochar surface through the increase of oxygen-containing functional groups enhanced the cadmium sorption capacity, and the sorption capacity increased by 21.2% in maximum. Roughed surface from oxidation was another reason for increasing cadmium adsorption. Results indicated that the adsorption performance of biochar on pollutant would be changed during aging process along with the changing surface properties.
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30435. 题目: Equilibrium sampling reveals increasing thermodynamic potential of polycyclic aromatic hydrocarbons during sewage sludge digestion
文章编号: N18052919
期刊: Chemosphere
作者: Karina K. Sjoeholm, Stine N. Schmidt, Annika Jahnke, Bo Svensmark, Philipp Mayer
更新时间: 2018-05-29
摘要: The reuse of digested sludge from wastewater treatment plants (WWTPs) as soil fertilizer poses a risk for contamination of soil and water environments. The present study provides a new approach for investigating the exposure of hydrophobic organic chemicals in sewage sludge. The methodology of equilibrium sampling with multiple thicknesses of silicone was successfully validated and applied to complex sludge matrices. Polycyclic aromatic hydrocarbon (PAH) concentrations in silicone (C silicone ) were determined and compared across four WWTPs. Activity ratios (ARs), defined as C silicone at equilibrium with digested sludge (final product) over C silicone at equilibrium with secondary sludge (intermediate product), were in the range 0.85–20 with all except one AR>1. These ARs thus revealed increased thermodynamic potential of both parent and alkylated PAHs in digested sludge compared with secondary sludge, and thereby higher exposure of PAHs in sludge after digestion than before digestion. This observation can be explained by the concept of “solvent depletion” as organic matter decreased by a factor of 1.3 during digestion, resulting in reduced sorptive capacity and increased freely dissolved concentrations (C free ). The PAHs with logK ow > 6 had ARs close to 1.3, whereas PAHs with logK ow < 6 showed higher ARs than the organic matter decrease factor of 1.3. C free in digested sludge were higher than reported in rural soil and generally consistent with levels reported for Baltic Sea sediment.
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30436. 题目: Influence of suspended sediment characteristics on the bioaccumulation and biological effects of citalopram in Daphnia magna
文章编号: N18052918
期刊: Chemosphere
作者: Haohan Yang, Guanghua Lu, Zhenhua Yan, Jianchao Liu, Huike Dong
更新时间: 2018-05-29
摘要: The influence of suspended sediment (SPS) characteristics on the bioavailability of the antidepressant citalopram (CIT) was investigated in the cladoceran Daphnia magna. The bioaccumulation, swimming behaviours, psychological indices, and oxidative stress were examined. The CIT bioaccumulation were altered in the presence of SPS, such that the body burden of CIT decreased as the concentration of SPS increased and as the organic carbon content of SPS (f oc ) increased; moreover, the body burden of CIT increased as SPS particle size increased. All the biomarker activities of D. magna were markedly induced at a CIT exposure concentration of 10 μg/L. However, the biological effects of CIT did not depend on the body burden of CIT as SPS concentration increased, while the swimming activities and oxidative stress were significantly enhanced by SPS concentration at 1 g/L. The influences of SPS particle size and f oc on the activities of swimming and physiological indicators were mainly associated with the CIT bioaccumulation, while f oc in SPS was more substantial than particle size. In addition, the antioxidant activities decreased as f oc increased and were significantly strengthened at particle sizes of 30–60 μm. The impacts of different SPS characteristics on the adsorption and desorption capacity of CIT and the ingestion habits of D. magna were the main reasons for the variations in CIT body burden and biological effects. According to the results obtained in this study, the SPS characteristics should be considered in the risk assessment of contaminants in natural aquatic environments.
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30437. 题目: Mechanisms of rice straw biochar effects on phosphorus sorption characteristics of acid upland red soils
文章编号: N18052917
期刊: Chemosphere
作者: Yong Liu, Zhi-Qiang Zhu, Xiao-Song He, Chao Yang, Ying-Qiong Du, Yong-Dong Huang, Peng Su, Shan Wang, Xiao-Xiao Zheng, Ya-Juan Xue
更新时间: 2018-05-29
摘要: An important pathway for biochar to alter the availability of soil phosphorus (P) is to change P sorption characteristics of the soil. The aim of this study was to understand the mechanisms of biochar effects on P sorption in acid upland red soils in the presence of different concentrations of exogenous P. Rice straw biochar (RSB) was prepared and applied at rates of 0, 1%, 3%, and 5% (w/w) to three red soils (MZ1, MZ2, and QY1) differing in initial pH (pH = 4.31, 4.82, and 5.68, respectively). The P sorption characteristics of these red soils were described using the Langmuir and Temkin equations and their relationships with soil basic physicochemical properties were analyzed. Furthermore, a representative red soil (MZ2) was selected to analyze the zeta potential of soil colloids and the chemical properties of sorption equilibrium solution, in order to understand their relationships with P sorption characteristics. Results showed that within a certain range of P concentration in the equilibrium solution, the amount of P sorbed by the three red soils decreased and the corresponding amount of P desorbed increased with increasing amendment rate of RSB. RSB showed the greatest effect on P desorption characteristics of MZ2 soil in the presence of higher exogenous P concentration. With increasing RSB amendment rate, the maximum P sorption of MZ1 soil decreased, while those of MZ2 and QY1 soils increased after an initial decrease. Phosphate sorption equilibrium constant and maximum P buffer capacity of each soil first increased and then decreased. However, a single physicochemical property could not interpret complex changes in multi-factors that jointly determine the P sorption characteristics of red soils. In the case of MZ2 soil, RSB amendment shifted the zeta potential of soil colloids to the negative direction; this decreased the positive charge and increased the negative charge on the soil surface, thus reducing P sorption in the MZ2 soil. In the presence of the same concentration of exogenous P, RSB amendment altered the pH, dissolved organic C (DOC), humification index (HIX), and maximum fluorescence intensity (Fmax) in the sorption equilibrium solution. In most cases, the amount of P sorbed by the MZ2 soil was negatively correlated with the pH value, DOC concentration, HIX value, and Fmax value of humic-like dissolved organic matter (DOM), and positively correlated with the Fmax value of protein-like DOM (P < 0.05 or P < 0.01). The relative fractional distribution of the contents for humic-like and protein-like DOM might determine the difference in the P sorption characteristics of MZ2 soil. In conclusion, different amendment rates of RSB affected the release of phosphate from soil surfaces into the solution by altering basic physicochemical and electrochemical properties of red soils and chemical properties of sorption equilibrium solution.
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30438. 题目: Organic matter decomposition before arsenic speciation analysis of water sample – “Soft decomposition” using nano-photocatalysts
文章编号: N18052916
期刊: Chemosphere
作者: Ewa Biaduń, Natalia Nowak, Joanna Kowalska, Krzysztof Miecznikowski, Beata Krasnod?bska-Ostr?ga
更新时间: 2018-05-29
摘要: The applicability of photolysis in the speciation analysis of arsenic is investigated. The use of nano scale semiconductors (Fe2O3/WO3/Fe2O3 at pH 6) as an active film during solar light irradiation of a water sample, containing some surfactants (SDS), results in the simplification of the organic matter and gives no speciation change in the arsenic. The reproducibility of active layer is shown to be high and the surface roughness of each photoactive sample and photocurrent do not differ by more than 6 and less than 8%, respectively. The procedure of sample pretreatment caused a minimum (8–10%) amount of speciation change, whilst the irradiation is no longer that 2 h. The study indicates that “soft decomposition” can be performed for as long as 4 h, and still give photostable arsenates (III) and methylarsenate species. However, the saturation of the water sample with Ar is required (to reduce the oxygen content) for the longer the decomposition time being applied.
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30439. 题目: Properties of magnetic carbon nanomaterials and application in removal organic dyes
文章编号: N18052915
期刊: Chemosphere
作者: Junhong Wang, Qiang Zhang, Xianzhao Shao, Jianqi Ma, Guanghui Tian
更新时间: 2018-05-29
摘要: Magnetic carbon nanomaterials were prepared facilely by one step hydrothermal synthesis method using biologically regenerated glucose as carbon sources and ferric ammonium citrate as iron sources. As-synthesized nanomaterials were characterized by means of SEM, TEM, XRD, N2 adsorption-desorption, VSM and XPS etc. techniques. Results show as-prepared magnetic nanomaterials are sphere particles with aggregation state and magnetic α-Fe particles are enclosed by carbon matrixes. With increase of calcination temperature, the degrees of the sample aggregation decrease, whereas the average particle sizes, BET specific surface areas and saturation magnetizations increase. The carbon with graphite structure has higher adsorption efficiency than that of amorphous carbon for organic dye rhodamine B in water. Whereas the iron with amorphous structure shows higher photocatalytic activity than that of the iron with crystalline structure for the degradation of rhodamine B. And rhodamine B in water can almost be degraded completely through the combination of adsorption and photocatalysis.

30440. 题目: Redistribution of Cs 137 introduced into montmorillonite in association with organic matter coming from biomass composting
文章编号: N18052914
期刊: Chemosphere
作者: J. Mihalik, M.J. Madruga, M.H. Casimiro, L.M. Ferreira, M.I. Prudêncio
更新时间: 2018-05-29
摘要: The adsorption and later bioavailability of 137Cs from the system humic acid (HA)/humic acid like compounds (HALC) and montmorillonite was investigated. The setup of the experiments should approach as much as possible natural conditions when 137Cs is introduced into soil with HALC from decomposed biomass. The significant differences were found in the trials containing various HA/HALC and also pure montmorillonite. The 137Cs was more available when it reached soil in association with HALC originated from compost than when it was adsorbed on stable humic acids. Moreover, the long term interaction of 137Cs with HALC led to decrease of 137Cs adsorbed on montmorillonite and increase of its bioavailable fraction. UV–Vis spectrometry and infrared spectroscopy showed the clear difference between HA, fresh HALC and old HALC which could partially explain the different results.
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