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所有论文

23421. 题目: Temporal trends of organic carbon accumulation in seagrass meadows from the northern Mexican Caribbean
文章编号: N20070108
期刊: Catena
作者: P.G. López-Mendoza, A.C. Ruiz-Fernández, J.A. Sanchez-Cabeza, B.I. van Tussenbroek, T. Cuellar-Martinez, L.H. Pérez-Bernal
更新时间: 2020-07-01
摘要:

Carbon sequestration in seagrass meadows mitigates the currently rising CO2 atmospheric levels, as these ecosystems are highly productive and preserve sediment organic carbon over long periods. Five 210Pb dated sediment cores, collected from seagrass meadows dominated by Thalassia testudinum in the northern Mexican Caribbean touristic corridor Cancun-Riviera Maya, were used to establish temporal trends of organic carbon (Corg) content, burial rates and stock variation over the past 100 years. Corg contents (0.17–1.94%) and burial rates (2.0–252 g m−2 yr−1) were generally within the lower end range reported for seagrass meadow sediments worldwide. Corg stock gradually increased over the past decades, associated with increasing sediment accumulation, possibly caused by inland erosion promoted by agricultural and forestry activities and, in the recent decades, by a rapid increase of urban development due to a fast growth of the tourist industry and population, likely causing fertilization of coastal waters. Seagrass meadow sediments in the northern Mexican Caribbean coastline showed long-term Corg storage and preservation, since ~ 40 to ~ 100 years depending on the core, which emphasizes the need to protect these ecosystems against impacts of global change, and their incorporation into climate change mitigation strategies should be considered.

23422. 题目: The effect of climatic and edaphic factors on soil organic carbon turnover in hummocks based on δ13C on the Qinghai-Tibet Plateau
文章编号: N20070107
期刊: Science of the Total Environment
作者: Hanzhi Li, Feng Yan, Dengfeng Tuo, Bin Yao, Junhan Chen
更新时间: 2020-07-01
摘要:

Hummocks (thúfur, pounus) are peculiar landforms usually formed by repeated freeze–thaw processes and differential frost heave, and are common in frost soil regions, especially in the Qinghai-Tibet Plateau. However, little is known about the response of δ13C in soil organic carbon (δ13CSOC) to soil and climate properties in hummocks. The β value indicates the decomposition rate of soil organic carbon (SOC) in soil, and was obtained from the slope of the regression between the log10-transformed SOC concentration and δ13CSOC in soil depth profiles. In this study, we investigated δ13CSOC and SOC contents along a soil profile (0–60 cm), together with edaphic and climatic properties, both in hummocks and control plots (alpine grasslands) on the northeastern Qinghai-Tibet Plateau. Then, the variations in δ13CSOC and β values, and the main factors affecting them, were analyzed. The results show that δ13CSOC increases with soil depth, while SOC decreases both in the hummocks and control plots. However, β values in the hummocks were significantly (P < 0.05) higher than in the control plots while δ13CSOC showed no difference between hummock and control. Redundancy analysis showed that altitude is the main control factor for δ13CSOC and β in the hummocks. Climate type was the main factor affecting δ13CSOC in the control plots, while mean annual precipitation and soil fractal dimension were the main factors controlling β. Overall, climate, rather than soil, is the key factor that affects the carbon turnover rate in the hummock in the northeastern QTP. The findings of this study will expand our understanding of the soil carbon cycle and δ13CSOC changes, especially in the case of hummocks.

23423. 题目: Effects of dam construction on arsenic mobility and transport in two large rivers in Tibet, China
文章编号: N20070106
期刊: Science of the Total Environment
作者: Zhenjie Zhao, Shehong Li, Lili Xue, Jie Liao, Jingjing Zhao, Mei Wu, Mingguo Wang, Jing Sun, Yan Zheng, Qiang Yang
更新时间: 2020-07-01
摘要:

Construction of dams on the Singe Tsangpo (ST) and the Yarlung Tsangpo (YT) Rivers, the upper stretch of the Indus and the Brahmaputra Rivers, respectively, are expected to affect material transport. To evaluate the effects of dam construction on arsenic (As) mobility and transport in the ST River and the YT River in Tibet and the downstream river basins, water column and sediment core samples in the Shiquan Reservoir of the ST River and in the Zam Reservoir of the YT River were obtained in August 2017, and January and May 2018, and additionally, at the inflows and outfalls of the reservoirs. The seasonal variation of dissolved As contents in the inflow water of the Zam Reservoir and the Shiquan Reservoir was regulated by the mixing between the low-As river runoff and the high-As hot spring input. Water residence time (WRT) is a key variable regulating the variation of dissolved As contents in reservoirs and outflow waters with time. The absence of the oxic layer at the sediment-water interface reduced the accumulation of As in surface sediments under high-flow conditions. Arsenic mobility in sediment of the two reservoirs was mainly controlled by Mn oxides and organic matter. Reservoirs with long water residence time are more favorable for As retention. Sedimentation was the main mechanism of As retention. The Shiquan Reservoir with a longer WRT of 385 days can effectively retain 55% of the total arsenic load from upstream, while the Zam Reservoir has no effective retention of arsenic due to the very short WRT of 1.1 days. These have important implications on the geochemical and ecological environments of the downstream river basins.

23424. 题目: Vermiremediation of cotton textile sludge by Eudrilus eugeniae: Insight into metal budgeting, chromium speciation, and humic substance interactions
文章编号: N20070105
期刊: Bioresource Technology
作者: Sarmistha Paul, Linee Goswami, Ratul Pegu, Satya Sundar Bhattacharya
更新时间: 2020-07-01
摘要:

Information on prospective metal remediation by Eudrilus eugeniae during vermicomposting of cotton textile sludge (CTS) is rather scarce. This investigation, therefore, evaluates the sanitization efficiency of this species in CTS and CTS + cow-dung (CD) based feedstocks against aerobic composting. Accordingly, reduction in Pb, Cd, Cr, and Zn concentrations was between 50 and 70% under vermicomposting. Budget equations substantiated that humic compound mediated chelation was the dominant route of metal removal, against nominal bioaccumulation by earthworms. Correlation statistics revealed that formation of humic compounds (humic acid, fulvic acid, and humin) greatly influenced the transition of toxic Cr6+ to benign Cr3+ during vermicomposting. Moreover, increase in total N content and P availability was significantly greater under vermicomposting than composting. Thus, E. eugeniae efficiently stabilized the feedstocks by reducing pH, Ca, S, and organic C and CTS + CD(2:1) was the most favorable feedstock for E. eugeniae vermicomposting in respect of metal detoxification and nutrient stabilization.

23425. 题目: Water management impact on denitrifier community and denitrification activity in a paddy soil at different growth stages of rice
文章编号: N20070104
期刊: Agricultural Water Management
作者: Wenjun Jin, Wenchao Cao, Fei Liang, Yongkang Wen, Fengwen Wang, Zhaorong Dong, He Song
更新时间: 2020-07-01
摘要:

Rice is one of the largest water-consuming crops. Alternate wetting and drying (AWD) is now an effective water-saving practice for rice cultivation that has been widely applied across the world. AWD may increase denitrification loss. However, the underlying mechanism remains unclear. This study investigated denitrifier activity, abundance and community structure in the rice rhizosphere and bulk soil in response to water management at the internode elongation (IE) and flowering (F) stages. The results revealed that at the IE stage, AWD significantly increased denitrification capacity (DC) in the rhizosphere compared with continuously flooded practice (CF). DC was significantly and positively related to electrical conductivity (EC) and the abundance of nirS-harboring denitrifiers. AWD led to higher EC in the 0–20 cm soil layer than CF. Although AWD lowered nirS abundance by 15 % compared with CF, the activity of nirS-harboring denitrifiers was enhanced by 1.89-folds of CF. At the F stage, AWD significantly decreased DC relative to CF. AWD had lower dissolved organic carbon (DOC) than CF, and DOC was significantly correlated with DC. Compared with CF, AWD also markedly changed the structure and network stability of nirS and nirK communities, resulting in sharp decreases in the total number of links in nirK and nirS networks of rhizosphere. The soil pH and EC were the key factors shaping the structure of nirS and nirK communities. Overall, the increase in denitrification losses due to AWD occurred primarily at the IE rather than F stage, and this increase was attributed to a rise in EC and changes in the activity and structure of nirS community. These findings provide a new insight into the mechanism of impact of the water-saving practice on denitrification loss for rice cultivation.

23426. 题目: Molecular composition and source apportionment of fine organic aerosols in Northeast China
文章编号: N20070103
期刊: Atmospheric Environment
作者: Xia Wu, Fang Cao, MdMozammel Haque, Mei-Yi Fan, Shi-Chun Zhang, Yan-Lin Zhang
更新时间: 2020-07-01
摘要:

We examined the characteristics and source apportionment of organic aerosols in ambient PM2.5 samples collected during the late autumn in Changchun, Northeast China. 8 compound classes (>90 individual species) were detected in the aerosol samples, including biomass burning tracers, aliphatic lipids (fatty acids and fatty alcohols), secondary oxidation products, polycyclic aromatic hydrocarbons (PAHs), sugar compounds, hopanes and biogenic secondary organic aerosol (SOA) tracers. The concentrations of total quantified organic species ranged from 138.2 to 6.8 × 103 ng m−3, among which levoglucosan was the most abundant compound. Biomass burning tracers (anhydrosugars, lignin and resin acids) were the most abundant compounds, followed by fatty acids, secondary oxidation products, PAHs, sugar compounds and fatty alcohols. Biogenic SOA tracers and hopanes were less abundant. The homohopane index [defined as 31abS/(31abS + 31abR)] was 0.5, indicating a potential contribution of traffic emission. PAHs showed a dominance of benzo(b)fluoranthene (BbF), and the diagnostic ratios implicated a substantial contribution of petroleum combustion as well as coal combustion. 2-methylglyceric acid to 2-methyltetrols ratio (2.2) indicated that NOx influence isoprene oxidation products formation. Furthermore, the average ratio of cis-pinonic acid plus pinic acid to 3-hydroxyglutaric acid (31.4) revealed the much fresher α/β-pinene oxidation products to some extent. A good correlation was found between β-caryophyllinic acid and levoglucosan (r = 0.61), suggesting that β-caryophyllene can mainly be generated by biomass burning. The biogenic secondary organic carbon (SOC) was underestimated by the tracer-based method, which only occupied 0.4% of the organic carbon (OC). In contrast, PMF model indicated that emissions from fossil fuel combustion and biomass burning were most important, accounting for 42.4% and 33.6%, respectively, followed by biogenic SOA emission (17.0%) and fungal spore derived source (7.0%), suggesting biogenic aerosol is a nonnegative contributor.

Capsule

Fossil fuel combustion (42.4%) as well as biomass burning (33.6%) were most important contributors of organic aerosols in a typical city in Northeast China.

23427. 题目: Revisiting afro-alpine Lake Garba Guracha in the Bale Mountains of Ethiopia: rationale, chronology, geochemistry, and paleoenvironmental implications
文章编号: N20070102
期刊: Journal of Paleolimnology
作者: L. Bittner, M. Bliedtner, D. Grady, G. Gil-Romera, C. Martin-Jones, B. Lemma, B. Mekonnen, H. F. Lamb, H. Yang, B. Glaser, S. Szidat, G. Salazar, N. L. Rose, L. Opgenoorth, G. Miehe, W. Zech, M. Zech
更新时间: 2020-07-01
摘要: Previous paleolimnological studies demonstrated that the sediments of Garba Guracha, situated at 3950 m asl in the afro-alpine zone of the Bale Mountains of Ethiopia, provide a complete Late Glacial and Holocene paleoclimate and environmental archive. We revisited Garba Guracha in order to retrieve new sediment cores and to apply new environmental proxies, e.g. charcoal, diatoms, biomarkers, and stable isotopes. Our chronology is established using 210Pb dating and radiocarbon dating of bulk sedimentary organic matter, bulk n-alkanes, and charcoal. Although bedrock was not reached during coring, basal ages confirm that sedimentation started at the earliest ~ 16 cal kyr BP. The absence of a systematic age offset for the n-alkanes suggests that pre-aging is not a prominent issue in this lake, which is characterised by a very small afro-alpine catchment. X-ray fluorescence scans and total organic carbon contents show a prominent transition from minerogenic to organic-rich sediments around 11 cal kyr BP coinciding with the Holocene onset. While an unambiguous terrestrial versus aquatic source identification seems challenging, the n-alkane-based Paq proxy, TOC/N ratios, δ13C values, and the sugar biomarker patterns suggest a predominantly autochthonous organic matter source. Supraregional climate events, such as the African Humid Period, the Younger Dryas (YD), a 6.5 cal kyr BP short drying event, and the 4.2 cal kyr BP transition to overall drier climate are recorded in our archive. The Garba Guracha record suggests that northern hemisphere forcings played a role in the Eastern African highland paleoclimate.

23428. 题目: Molecular Characterization of Water‐soluble Brown Carbon Chromophores in Beijing, China
文章编号: N20070101
期刊: Journal of Geophysical Research: Atmospheres
作者: Caiqing Yan, Mei Zheng, Yury Desyaterik, Amy P. Sullivan, Yusheng Wu, Jeffrey L. Collett
更新时间: 2020-07-01
摘要:

High abundance and strong light absorption of atmospheric brown carbon (BrC) have been reported in East Asia, especially in northern China. However, the molecular‐level understanding of BrC chromophores in this area are still limited and quite challenging. In this study, elemental composition of individual BrC chromophores were first investigated in the megacity of Beijing, China, using a powerful platform for the characterization of BrC chromophores, with combination of high‐performance liquid chromatography coupled to a UV/Vis absorbance detector and a time‐of‐flight mass spectrometer with an electrospray ionization source (LC/DAD‐ESI‐HR‐TOFMS). The results from this study showed that S‐containing compounds (e.g., CHOS and CHONS) significantly increased in highly polluted days compared to lightly polluted days, probably due to increased emissions from sources such as coal combustion and favorable conditions for organosulfates formation. It was found that CHON and CHO compounds were the most abundant water‐soluble organic compounds in Beijing especially during the wintertime. Nitro‐aromatic compounds were the major water‐soluble BrC chromophores, with three major BrC chromophores (e.g., C6H5NO3, C7H7NO4, and C6H5NO4) found under all conditions, while other specific BrC chromophores with CHON‐ and CHO‐containing elemental formulas identified and varied in different seasons and pollution conditions. Overall, the water‐soluble BrC chromophores identified in this study explained about 2‐18% of the bulk BrC absorbance over the wavelength range of 300‐400 nm. In‐depth studies on exploring more BrC chromophores as well as their chemical structures, related sources and formation mechanisms should be conducted in the future.

23429. 题目: A new in-field indicator to assess the impact of land management on soil carbon dynamics
文章编号: N20063007
期刊: Geoderma
作者: Alexis Thoumazeau, Tiphaine Chevallier, Victor Baron, Nancy Rakotondrazafy, Phantip Panklang, Raphaël Marichal, Mark Kibblewhite, David Sebag, Florent Tivet, Cécile Bessou, Frédéric Gay, Alain Brauman
更新时间: 2020-06-30
摘要:

The assessment of the impacts of land-use and management on soil organic carbon (SOC) dynamics is a major environmental concern, as the soil carbon cycle underpins key ecosystem services. However, assessments based on short-term SOC dynamics face methodological and experimental difficulties. Hurisso et al. (2016) proposed a method to assess SOC dynamics by coupling two methods: Permanganate Oxidizable Carbon (POXC) and Basal Soil Respiration (BSR). This method has been used in laboratory on dried and re-wetted soil samples from temperate regions mainly. In our study, we adapted this method to the field and proposed a cost-effective in-field indicator combining the POXC and in situ Basal Soil Respiration (SituResp® method).

We tested the indicator at four study sites (n = 169 points) within various tropical land-use and management contexts based on rubber, soybean and oil palm cropping systems respectively in Thailand, Cambodia and Indonesia. The results demonstrated the relevance, sensitivity and robustness of the POXC-SituResp® indicator to characterize the impact of a gradient of disturbance on SOC dynamics. The results also highlighted the potential of conservation agriculture (no-tillage and crops residues) and compost amendments to accumulate SOC. Rock-Eval® analysis showed that POXC-SituResp® indicator is negatively linked to excess of potentially mineralizable labile carbon. Carbon pools targeted by the POXC were specified by Rock-Eval® pyrolysis measurements to be a rather thermal resistant pool of SOC.

Our study confirms that the integrated indicator based on POXC and BSR assess a relative carbon stabilization of SOC pools. This indicator can be measured in the field by a rapid and cost-effective method.

23430. 题目: Chemical and physical characterization of spent coffee ground biochar treated by a wet oxidation method for the production of a coke substitute
文章编号: N20063006
期刊: Waste Management
作者: Zelma Maree, Christien A. Strydom, John R. Bunt
更新时间: 2020-06-30
摘要:

Coke production relies on the availability, cost and quality of coking coal. Depleting coking coal resources and environmental pressure force the metallurgical industry to search for alternative methods to produce coke. Waste spent coffee grounds (biomass) treated via hydrothermal liquefaction (HTL) is an energy-efficient method to produce biochar. In this study the use of HTL biochar as feedstock for the production of a coke substitute was investigated. Wet oxidation treatment of the prepared biochar samples was done with different wet oxidant hydrogen peroxide concentrations (5, 15, 30%). The biochar was treated for different time durations (0.5, 1, 2, 6 and 24 h) and at different temperatures (room temperature and 80 °C). Thereafter, the various samples were characterized and pyrolysed to obtain a coke substitute. Characterization of the various samples before and after thermal treatment was done using Fourier-transform infrared spectroscopy (FTIR), free swelling index, ultimate and proximate analysis, gross calorific value and compressive strength determination. The investigated characteristics of the produced coke substitute obtained from the pyrolysed biochar treated for 24 h with 30 vol% H2O2 at room temperature, showed the most promising results when compared to blast furnace coke.

23431. 题目: The remediation of urban freshwater sediment by humic-reducing activated sludge
文章编号: N20063005
期刊: Environmental Pollution
作者: Meng Li, Jingmei Sun, Chang Liu, Yinqi Tang, Jianjun Huang
更新时间: 2020-06-30
摘要:

Organic pollution of urban rivers caused by stormwater discharge is a global problem. Traditional bioremediation of organic matters (OM) by aerobes could be restrained in anaerobic environments, which usually occurr in polluted river sediments. In this study, an anaerobic remediation technology has been developed to enhance the in-situ removal of organic matters in river sediments, humic-reducing sludge (HRS) was adapted from traditional activated sludge; it exhibited a strong humic-reducing ability. Nitrate and biostimulants were used to stimulate HRS. The change of microbial community between AQDS-adapted and non-AQDS-adapted was analyzed, and the effect of HRS augmentation and Nitrate/biostimulant addition on TOM removal were discussed from the perspective of light and heavy fraction organic matters (LFOM and HFOM). The results have indicated that, after adaptation, HRS had increased the bacterial population of Anaerolineales and Desulfuromonadales, which was related to the carbon metabolism and electron-transfer ability. On the other hand, the adaptation decreased the population of bacteria related to the sulfur/sulfate circulation. This characteristic of the HRS was potentially benificial to reducing the occurrence of black-odor phenomenon. Also, the removal efficiency of TOM in sediment was significantly improved by using HRS because HRS could facilitate the removal of HFOM. Fourier Transform Infrared Spectroscopy (FTIR) analysis indicated that the advantage of decomposing HFOM using HRS resulted from the fact that the HFOM contained redox mediators to facilitate humic-reducing respiration. In addition, nitrate appeared to be crucial for the enhancement of HRS in sediments. These findings have allowed for the development of a technology for in-situ anaerobic remediation of urban river sediments. They could also help to understand humic-reducing mechanism in the sediment during anaerobic bioremediation.

23432. 题目: The driving factors of mercury storage in the Tibetan grassland soils underlain by permafrost
文章编号: N20063004
期刊: Environmental Pollution
作者: Jing Gu, Qiaotong Pang, Jinzhi Ding, Runsheng Yin, Yuanhe Yang, Yanxu Zhang
更新时间: 2020-06-30
摘要:

Soils, especially permafrost in the Arctic and the Tibetan Plateau, are one of the largest reservoirs of mercury (Hg) in the global environment. The Hg concentration in the grassland soils over the Tibetan Plateau and its driving factors have been less studied. This study analyzes soil total mercury (STHg) concentrations and its vertical distribution in grassland soil samples collected from the Tibetan Plateau. We adopt a nested-grid high-resolution GEOS-Chem model to simulate atmospheric Hg deposition. The relationship between STHg and soil organic carbon (SOC), as well as atmospheric deposition, are explored. Our results show that the STHg concentrations in the Tibetan Plateau are 19.8 ± 12.2 ng/g. The concentrations are higher in the south and lower in the north in the Tibetan Plateau, consistent with the previous results. Our model shows that the average deposition flux of Hg is 3.3 μg m−2 yr−1, with 57% contributed by dry deposition of elemental mercury (Hg0), followed by dry (19%) and wet (24%) deposition of divalent mercury. We calculate the Hg to carbon ratio (RHg:C) as 5.6 ± 6.5 μg Hg/g C, and the estimated STHg is 86.6 ± 101.2 Gg in alpine grasslands in the Tibetan Plateau. We find a positive relationship between STHg and SOC in the Tibetan Plateau (r2 = 0.36) and a similar positive relationship between STHg and atmospheric total Hg deposition (r2 = 0.24). A multiple linear regression involving both variables better model the observed STHg (r2 = 0.42). We conclude that SOC and atmospheric deposition influence STHg simultaneously in this region. The data provides information to quantify the size of the soil Hg pool in the Tibetan Plateau further, which has important implications for the Hg cycles in the permafrost regions as well as on the global scale.

23433. 题目: P-nitrophenol degradation by pine-wood derived biochar: The role of redox-active moieties and pore structures
文章编号: N20063003
期刊: Science of the Total Environment
作者: Shihui Feng, Peng Zhang, Wenyan Duan, Hao Li, Quan Chen, Jing Li, Bo Pan
更新时间: 2020-06-30
摘要:

Biochar can both adsorb and degrade p-nitrophenol (PNP); however, the PNP degradation mechanism has not been well investigated. We prepared two biochars at pyrolysis temperatures of 500 °C (B500) and 700 °C (B700). Although B500 showed much stronger free radical signals (which are associated with organic degradation, according to previous studies), the apparent PNP degradation was approximately 3 times higher in the B700 system. The degradation increased significantly after the biochars were washed with water. According to a quantitative analysis of the sorption and degradation and two-compartment first-order kinetics modeling of the apparent removal kinetics, sorption occurred mainly in the initial period, whereas degradation continued throughout the removal process. The PNP degradation rate constant depended mainly on the external surface area at a relatively low concentration (200 mg/L) and was controlled by the microporous surface area at a relatively high concentration (800 mg/L). In addition, the apparent degradation did not depend on the biochar particle size. Therefore, PNP degradation may be related to the three-dimensional structure of the biochar in addition to the exposed external surface. The well-developed pore structure, more accessible surface, and larger electron exchange capacity of B700 may promote electron transfer between the biochar and PNP, and thus accelerate PNP degradation. This study demonstrates that various properties of the biochar may contribute to PNP degradation.

23434. 题目: Optimization of the Coagulation–Flocculation Process for Slaughterhouse Wastewater Using Response Surface Methodology
文章编号: N20063002
期刊: Clean - Soil, Air, Water
作者: Öznur Begüm Gökçek, Safiye Özdemir
更新时间: 2020-06-30
摘要:

Slaughterhouse wastewater is one of the main sources of environmental pollutants, containing a high amount of organic matter (chemical oxygen demand (COD), biochemical oxygen demand (BOD)), total nitrogen, total suspended solids, total phosphorus, grease, and oil. The main aim of the present research is optimizing the coagulation–flocculation process and examining the effects of experimental factors with each other, e.g. pH, the concentration of two different coagulants (FeCl3 and alum), rapid mixing rate, and settling time. Therefore, it is aimed to treat slaughterhouse wastewater using the coagulation–flocculation process with the optimization of the response surface methodology (RSM). COD, turbidity, and suspended solids (SS) of the treated wastewater were chosen as the response variables. Furthermore, the optimal conditions for three responses were acquired by employing the desirability function approach. When the experimental results of two coagulants were compared, it was observed that the alum coagulant gave better results for the three responses. The alum coagulant utilized in the present research was able to increase COD, SS, and turbidity removal efficiency by 75.25, 90.16, and 91.18%, respectively. It is possible to optimize coagulation–flocculation by utilizing the RSM analysis, which proves that coagulation can pre‐treat slaughterhouse wastewater.

This article is protected by copyright. All rights reserved

23435. 题目: Effects of humus on the mobility of arsenic in tailing soil and the thiol-modification of humus
文章编号: N20063001
期刊: Chemosphere
作者: Yunfeng Xu, Kaili Wang, Qinghao Zhou, Liting Zhang, Guangren Qian
更新时间: 2020-06-30
摘要:

The ability of thiol-modified humic acids (HAs) to release arsenic in tailings soil after being modified with different sulfur-containing reagents were significantly improved. The structure and physicochemical properties of humic acid (HA) before and after thiol-modification were characterized. The 3-MPTS-HA treated with 3-mercaptopropyltrimethoxysilane (3-MPTS) effectively improved the mobility of arsenic, and its reducing ability was increased from 2 mmol g−1 to 3.54 mmol g−1. The S content of humic acids were also significantly increased after treatment with sulfur-containing reagents, in which the oxygen-containing functional group (e.g., C = O, C–O) on the surface of HA may be the active sites for binding with sulfur-containing reagents. It was found in the XPS spectrum that because the thiol group is easily oxidized, there are many S forms in thiol-modified HA. The –SH content in Na2S·9H2O-HA, l (+)-Cysteine-HA (Cys-HA), thioglycolic acid (TGA-HA) and 3-MPTS-HA was determined by fluorescence method to be 13.9, 78.45, 90.34, and 192.29 μmol g−1, respectively. The study demonstrated that surface thiol modification can increase the abundance of thiol in HA and enhance reactivity, which will further promote the application of HA in the treatment of heavy metal contaminated tailing soil.

23436. 题目: Identifying key drivers for geospatial variation of grain micronutrient concentrations in major maize production regions of China
文章编号: N20062905
期刊: Environmental Pollution
作者: Qing-Yue Zhao, Shi-Jie Xu, Wu-Shuai Zhang, Zhe Zhang, Zhi Yao, Xin-Ping Chen, Chun-Qin Zou
更新时间: 2020-06-29
摘要:

Micronutrient deficiencies are prevalent health problems worldwide. The maintenance of adequate concentrations of micronutrients in maize grain is crucial for human health. We investigated the overall status and geospatial variation of micronutrients in Chinese maize grains and identified their key drivers. A field survey was conducted in four major maize production areas of China in 2017 with 995 pairs of soil and grain samples collected from famers' fields. At a national scale, grain zinc (Zn), iron (Fe), manganese (Mn) and copper (Cu) concentrations varied substantially, with average values of 17.4, 17.3, 4.9, and 1.5 mg kg−1, respectively, suggesting a solid gap between grain Zn and Fe concentrations and the biofortification target values. Significant regional difference in the concentrations of Zn, Mn and Cu, but not Fe, were observed in grain, with much higher levels in Southwest China. The nutritional yields of Zn, Fe and Cu were lower than the energy and Mn yields, indicating an unbalanced outcome between energy and micronutrients in current maize production system. Grain Zn, Fe, Mn and Cu correlated negatively with maize yield in most test regions. Increased nitrogen (N) rate positively affected grain Zn and Cu, while increased phosphorus (P) rate negatively affects grain Zn and Fe. Apart from Fe, available Zn, Mn and Cu in soil exerted significant positive effects on grain Zn, Mn and Cu concentrations, respectively. Decrease in soil pH and increase in the organic matter content may increase the accumulation of Fe and Mn in grain. Grain Zn and Cu concentrations increased as available soil P decreased. Of the factors considered in this study, grain yield, N and P rates, soil pH and organic matter were the main factors that affect grain micronutrient status and should be more extensively considered in the production and nutritional quality of maize grain.

23437. 题目: Red mud modified sludge biochar for the activation of peroxymonosulfate: Singlet oxygen dominated mechanism and toxicity prediction
文章编号: N20062904
期刊: Science of the Total Environment
作者: Jia Wang, Min Shen, Hailong Wang, Yusheng Du, Xinquan Zhou, Zhuwei Liao, Huabin Wang, Zhuqi Chen
更新时间: 2020-06-29
摘要:

In this paper, red mud-sewage sludge derived biochar (RSDBC) was synthesized and employed as the heterogenous activator of peroxymonosulfate (PMS) for sulfamethoxazole (SMX) degradation. With the incorporation of red mud, 82.5% degradation of SMX was achieved by RSDBC/PMS system in a process dominated by 1O2, which was attributed to the participation of oxygen vacancy, ketone groups and graphitic carbon. On the other hand, in the absence of red mud, OH and SO4•− were dominantly accounted for SMX degradation in sewage sludge derived biochar (SDBC)/PMS system. In this case heterogeneous Fe species, ketone groups and graphitic carbon were responsible for PMS activation. Due to the different Reactive Oxygen Species (ROS), effects of reaction conditions including initial pH, common anions and natural organic matter (NOM) were not in full accord. Besides, Fe leaching from RSDBC (0.67 ppm) was much lower than that of SDBC (3.07 ppm), leading to a better reuse ability for RSDBC. Less degradation intermediates were disclosed in RSDBC/PMS system, along with lower residual toxicity. In addition, eco-toxicity of all the intermediates was predicted by ECOSAR program for the further understanding of the detoxification of SMX. Advantages of RSDBC/PMS system as disclosed in this paper further suggest its potential full-scale application of environmental remediation.

23438. 题目: Recycling application of waste long-root Eichhornia crassipes in the heavy metal removal using oxidized biochar derived as adsorbents
文章编号: N20062903
期刊: Bioresource Technology
作者: Sen Lin, Weiwei Huang, Hongjun Yang, Shuying Sun, Jianguo Yu
更新时间: 2020-06-29
摘要:

An oxidized biochar was prepared using long-root Eichhornia crassipes through an aerobic/anaerobic hybrid calcination to recycle its waste plants after eutrophic treatments. The adsorption performances of the biochar were investigated and the results showed that the adsorption equilibrium could arrive in 30 min and the adsorption capacities for Pb2+, Cu2+, Cd2+ and Zn2+ at 30°C were 0.57, 0.41, 0.44 and 0.48 mmol/g, respectively. The adsorption could be promoted at higher pH and temperature and the adsorption tolerance for different heavy metal ions to the existence of competing ions and organic matters was hierarchical. The adsorption was deduced to be heterozygous courses and mainly controlled by complexation of oxygen-containing groups with these heavy metal ions. It was confirmed that the biochar could be regenerated with HCl solution and the adsorption performance kept consistent in 10 adsorption-desorption cycles.

23439. 题目: Soil Organic Matter Dynamics as Affected by Land Use Change from Rice Paddy to Wetland
文章编号: N20062902
期刊: Wetlands
作者: Xian Wu, Toan Nguyen-Sy, Zheng Sun, Toru Wantanabe, Keitaro Tawaraya, Ronggui Hu, Weiguo Cheng
更新时间: 2020-06-29
摘要: The objective of this study was to investigate the impact of land use change, from rice paddy to natural wetland, on soil organic matter dynamics 12 years after the former was abandoned. Cold water extracted organic carbon (CWEOC) and hot water extracted organic carbon (HWEOC) obtained from surface and subsurface soil layers were measured as important indexes, reflecting organic matter dynamics. The quality of CWEOC and HWEOC was characterized by UV absorbance and parallel factor analysis (PARAFAC) modeling of fluorescence excitation-emission matrices (FEEMs). The results showed the land use change didn't significantly alter the quantity of SOC in all layer, but decrease the concentrations of CWEOC and HWEOC whereas the δ13C values appeared to increase. It suggested the carbon input into soil induced the change of DOC. The SUVA254 results showed aromatic content of DOC was less abundant in rice paddy, indicating DOC from paddy soil is more labile. The FEEM analysis suggested extracts from the rice paddy surface and wetland subsurface layers contain more humic-like fluorophores, while higher abundances of the tryptophan-like fluorophore were found in rice paddy subsurface and wetland surface layers. Overall, converting rice paddy to wetland didn't alter the stock of SOC; however, it significantly decreased the stock and stability of dissolved organic carbon.

23440. 题目: Variation in the properties of biochars produced by mixing agricultural residues and mineral soils for agricultural application
文章编号: N20062901
期刊: Waste Management and Research
作者: Stella Cristiani Gonçalves Matoso, Paulo Guilherme Salvador Wadt, Valdomiro Severino de Souza Júnior, Xosé Lois Otero Pérez, Fábio Plotegher
更新时间: 2020-06-29
摘要: The research and application of biochars enriched with minerals have increased in recent years; however, the mineral fraction used consists of specific minerals, such as clay minerals and synthesized compounds. In this work, the effects of adding two specific soil types (sandy and clayey) to rice and coffee husks in order to generate biochars via pyrolysis was investigated. Chemical, physical–chemical, thermal, spectroscopic and crystallographic analyses were conducted on the produced biochars. The study confirmed that the presence of mineral soils during the pyrolysis process increases the yield, C retention ratio, and specific surface area. It also decreases the pH, cation exchange capacity (CEC), nutrient content, and carbon-to-nitrogen ratio of biochars. However, the biochars produced by mixing coffee husks and mineral soils still demonstrate a capacity to increase the pH and the CEC of tropical soils. In addition, increased C retention demonstrates an environmental benefit of this biochar production method. Biomass pyrolysis combined with clayey soil results in a biochar with a higher degree of aromaticity and higher thermal stability when compared to biomass pyrolysis alone. These characteristics give the biochar a recalcitrant character, without the necessity for steps related to the synthesis of specific mineral compounds, which reduces the economic and energy cost of the process.

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