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41. 题目: The versatility of microbial fuel cells as tools for organic matter monitoring Water monitoring and remediation require robust, low-cost, and reliable test systems that can couple with prompt treatment interventions. Organic matter (BOD, COD), toxicants, heavy metals, and other pollutants in water need to be regularly inspected. Microbial fuel cells (MFCs) have already gained popularity as BOD biomonitoring systems as these don't need an external transducer or power source. Moreover, these systems are cost-effective, compact, biodegradable, reusable, portable, and applicable for on-site measurements. MFCs truly stands out as online BOD measurement devices as they provide wide detection range (0-25 g/L), low response time (2-4 min) and longer stability in continuous operations (2-5 years) in a cost-effective approach. This review examines the benefits, kinds, performance metrics, and signal optimization of the current state-of-the-art of the BOD measurement, with detailed focus on MFC-based BOD biomonitoring systems. This review covers the important technological breakthroughs in practical applications with associated bottlenecks to develop reliable sensing systems. | |||||
42. 题目: Lipid biomarker comparison of relict and active microbial mats from the McMurdo Ice Shelf, Antarctica Earth’s biota leave traces in the form of molecular fossils, typically from the membrane lipids of organisms, preserved in the sedimentary rock record. However, since the environmental conditions prevailing at the time can impact the nature of those remains, it is important to understand the diagenetic processes that occur under contrasting regimes. In this study, we investigated the preservation under cold and arid climatic conditions of intact polar lipids, bacteriohopanepolyols, and quinones preserved in a ∼700-year-old relict, desiccated microbial mat. We compared these to lipid signatures in actively growing counterparts from nearby meltwater ponds of McMurdo Ice Shelf in Antarctica. Substantial differences in lipid distribution were evident between active and relict mats, suggesting that significant diagenetic degradation of lipid biomarkers occurs within a short period, thereby illuminating the selective preservation of certain polar compound classes under cold and dry conditions. | |||||
43. 题目: Global sea level changes or local tectonics? Pliocene, Miocene and Oligocene biomarkers in cored sedimentary rocks from IODP Expedition 317, Canterbury Basin, New Zealand The various influences of global sea level (eustasy) and local tectonic changes on sedimentation processes in continental margin deposits are important topics in sedimentary research. International Ocean Discovery Program Expedition 317 to the Canterbury Basin, on the eastern margin of the South Island of New Zealand, provided an opportunity to study sediment geochemistry in contrasting depositional settings, from mid-shelf to upper continental slope sedimentary rocks from the Eocene to the Holocene. This paper provides the first examination of the organic geochemical record from Pliocene, Miocene, and Oligocene sediment samples recovered during the expedition from the U1351, U1352, and U1353 sites, using bulk geochemistry and hydrocarbon distributions, including biomarkers. The main aim of this research was to correlate changes in organic accumulation with local tectonic activity and global climate changes that occurred in the Miocene. There is good preservation of C11 to C35 n-alkanes, with varying predominance of odd-over-even chain length n-alkanes, and much variation in the terrigenous/aquatic ratio over the cores. Based on biomarker and Rock Eval parameters, thermal maturity varies from low in the Pliocene, to early oil window in the deeper Miocene and Oligocene sedimentary rocks. The pristane/phytane ratios for the three cores indicate anoxic to oxic depositional environments. Marine organic matter input is indicated by the high C30 sterane index, whilst high relative amounts of oleanane, C24 tetracyclic terpane, and C29 steranes indicates major terrigenous organic matter input. Local tectonic activity is suggested to have had a significant influence on the accumulation of the organic matter in the Canterbury Basin. The influence of eustasy and global sea temperature variations are suggested for the periods < 14 Ma, 12–7 Ma, and ∼6 Ma. An increase in terrigenous organic matter input during the late Miocene correlates with the uplift of the Southern Alps and an increase in the continental slope angle for the South Island of New Zealand. | |||||
44. 题目: Calcium enhances phosphorus reclamation during biochar formation: Mechanisms and potential application as a phosphorus fertilizer in a paddy soil Transformation of phosphorus (P) species during pyrolytic production of biochar from P-rich biowastes with a subsequent soil amendment is important to P reclamation. Aiming at increasing the content of plant-available P and restraining the formation of easily mobile P in pyrolysis product, this study used exogenous calcium ions (20 wt% CaCl2) addition prior to pyrolysis to regulate the pyrolytic transformation of P chemical fractions from sewage sludge and bone dreg. Results showed that active Ca catalyzed the decomposition of organic P to transform into inorganic orthophosphate. Based on Hedley’s sequential extraction method, this study found that addition of Ca ions remarkably reduced the content of soluble P, exchange P, Fe/Al bound P, and occluded P in biochar, while increased Ca bound P from 78 to 85% to 85–96%. Liquid 31P NMR indicated that exogenous Ca induced the crack of the P-O-P bond in pyrophosphate to become orthophosphates. It also explained why new orthophosphates including chlorapatite (Ca5(PO4)3Cl) and calcium hydroxyapatite (Ca10(PO4)6(OH)2) appeared in the Ca-composite biochar compared to pristine biochar. Combined with rapid P-release test in paddy soil (pH 6.27) and 30-days rice seedling growth test under flooded condition (10 wt% biochar addition ratio), it was confirmed that compared to pristine biochar, Ca-composite biochar released more P in paddy soil, but also promoted more P to be taken in by rice root and stalk. These results suggested that pretreating biowaste with Ca ion was a friendly approach to enhance P reclamation during biochar formation, making it a promising P fertilizer. | |||||
45. 题目: Dual Role of Soil-derived Dissolved Organic Matter in the Sulfamethoxazole Oxidation by Manganese Oxide Manganese oxides (MnO2) can mediate organic pollutant oxidation in aquatic environments, which has been reported to be inhibited or promoted by dissolved organic matter (DOM) in different studies. It remains unresolved why conflicting results have been observed and whether such results depend on the type and concentration of DOM. Here, we used three types of well-characterized DOM derived from soil heated at 50, 250, or 400°C (DOM_50, DOM_250, and DOM_400, respectively) to evaluate the impacts of DOM type and concentration and environmental pH on MnO2-mediated oxidation of sulfamethoxazole, a widely detected and ecotoxic emerging pollutant. We observed that the degradation rate of sulfamethoxazole was possibly promoted by DOM_250 (pH 6‒8), while it was generally inhibited by DOM_50 and DOM_400. Furthermore, it was initially inhibited and then promoted with increasing DOM concentrations and was consistently less inhibited at a higher pH. The inter-DOM variations of sulfamethoxazole degradation could be explained by the more enriched polyphenolics in DOM_250 than in DOM_50 and DOM_400, whereas the weak promoting effect of DOM_400 indicates that high DOM aromaticity may not necessarily promote pollutant degradation. Our results reconcile the debate on the role of DOM in the oxidation of sulfamethoxazole by MnO2 and highlight the decisiveness of the molecular composition and concentration of DOM and the reaction pH in the overall promoting or inhibiting role of DOM. | |||||
46. 题目: CO2 capture using biochar derived from conditioned sludge via pyrolysis To reduce pollution and simultaneously mitigate carbon emission. Biochar samples were prepared via the pyrolysis of sludge after conditioning with K2FeO4 and cationic polyacrylamide (CPAM) or chitosan (CTS), and their CO2 capture performance was compared. The optimal preparation conditions were 600 °C and 80 mg/g dry solid (DS) for K2FeO4, 20 mg/L for CPAM, and 1 mg/g DS for CTS. The results showed that the CO2 capture capacity of the biochar with K2FeO4 (K2FeO4-B) increased from 75.69 mg/g to 81.68 mg/g compared to RSB, the CO2 capture capacity of the biochar with PF+CPAM (K2FeO4-CPAM-B) was 94.81mg/g, and the CO2 capture capacity of the biochar with PF+CTS (K2FeO4-CTS-B) was 86.56 mg/g. The CO2 capture capacity of the biochar (K2FeO4-CTS-B) was 86.56 mg/g. The main reason for this improved capacity is that the addition of K2FeO4 and CPAM enhanced chemical properties of the biochar surface (carbon content, N–H content, etc.). Additionally, the biochar conditioned with K2FeO4 and CPAM demonstrated better cyclic adsorption performance and economic efficiency than the other samples. It has the prospect of engineering application. This study provides a reference for the selection of conditioning agents for wastewater treatment plants and a new solution for sludge disposal. | |||||
47. 题目: Evaluating the effects of formation and stabilization of opal/sand aggregates with organic matter amendments Opal (SiO2·nH2O, amorphous silica), the by-product of alumina extraction from coal fly ash (CFA), has a strong adsorption capacity and is also an important component of clay minerals in soils. The combining of opal with sand to form artificial soils is an effective disposal strategy for large-scale CFA stockpiles and reduction of environmental risk. Nevertheless, its poor physical condition limits plant growth. Organic matter (OM) amendments have broad potential applications for water-holding and improving soil aggregation. Effects of OMs (vermicompost (VC), bagasse (BA), biochar (BC) and humic acid (HA)) on the formation, stability and pore characteristics of opal/sand aggregates were evaluated through 60-day laboratory incubation experiments. Results demonstrated that four OMs could reduce pH, with BC having the most significant effect, VC significantly increasing the electrical conductivity (EC) and TOC content of the aggregates. Except for HA, other OMs could improve the aggregates' water-holding capacity. The mean weight diameter (MWD) and percentage of >0.25 mm aggregates (R0.25) of BA-treated aggregates were the largest, and BA had the most noticeable contribution to macro-aggregate's formation. The best aggregate stability was obtained with HA treatment, meanwhile the percentage of aggregate destruction (PAD0.25) decreased with the addition of HA. After amendments, the proportion of organic functional groups increased, which favored aggregate's formation and stability; the surface pore characteristics were improved, with the porosity ranging from 70% to 75%, reaching the level of well-structured soil. Overall, the addition of VC and HA can effectively promote aggregates' formation and stabilization. This research may play a key role in converting CFA or opal into artificial soil. The combining of opal with sand to form artificial soil will not only solve the environmental problems caused by large-scale CFA stockpiles but will also enable the comprehensive utilization of siliceous materials in agriculture. | |||||
48. 题目: Transformation kinetics of exogenous nickel in a paddy soil during anoxic-oxic alteration: Roles of organic matter and iron oxides Nickel is generally released from flooded soils; however, the key Ni transformation processes in soils that are freshly contaminated by Ni2+ during anoxic–oxic alteration remain unclear. We developed a kinetic model to investigate the Ni transformation in paddy soils under anoxic and oxic conditions based on the results of the seven-step sequential extraction, determination of dissolved and soil organic matter, and surface site quantification, which provide the kinetic data of different Ni fractions, organic matter, and reactive sites for modeling. The dissolved, exchangeable, and specifically adsorbed Ni was gradually transferred to fulvic complex, humic complex, Fe–Mn oxide bound, and sulfide bound Ni after 40 d of anoxic incubation due to the increase in pH and soil surface sites, which were mainly induced by Fe(III) oxide reduction and soil organic matter release. The introduction of oxygen triggered a rapid release of Ni, which was ascribed to the decrease in pH and soil surface sites caused by Fe(II) oxidation and carbon re-immobilization. Kinetic modeling demonstrated that complexation with soil organic matter dominated Ni immobilization under anoxic conditions, while organic matter and Fe–Mn oxides contributed similarly to Ni release under oxic conditions, although the majority of Ni remained complexed with soil organic matter. These findings are important for the evaluation and prediction of Ni behavior in paddy soils with exogenous Ni during flooding-drainage practices. | |||||
49. 题目: Effects of contrasting N-enriched biochar applications on paddy soil and rice leaf phosphorus fractions in subtropical China Biochar has been proved to be an important soil amendment to alleviate soil phosphorus (P) in the paddy crops. However, the role of specially prepared biochar (N-enriched biochar) on the distribution and transformation of P soil in and rice leaves needs to be revealed. In this study, we studied in a field experiment the effects of two different levels of application of N-enriched biochar on the P fractions of soil and leaves. The results showed that: (1) in early rice, both rates of N-enriched biochar increased soil concentrations of labile inorganic P (Pi) (+51.5 % and +66.2 %, respectively) and labile organic P (Po) (+167 % and + 76.9 %, respectively) and moderately labile Pi (+37.8 % and +27.8 %, respectively) and decreased soil concentration of moderately labile Po (−17.0 % and −52.7 %, respectively) in the 0–15 cm layer. Soil total P concentration was positively correlated with soil labile P fractions and moderately labile Pi concentrations (p < 0.05); (2) in early and late rice, application of the biochar at 4 t ha−1 increased rice leaf concentration of inorganic (+13.3 % and +34.8 %, respectively), nucleic acid (+24.2 % and +13.0 %, respectively) (p < 0.05). The foliar inorganic and nucleic acid P concentrations were positively correlated with foliar total P concentrations; (3) redundancy analysis showed that with the application of N-enriched biochar, soil total carbon (C), nitrogen (N) and P concentration were important factors affecting the chemical forms of soil P, while soil organic matter, soil total P and leaf total P content were important factors affecting the chemical forms of leaf P; (4) allometric growth models showed that under the application of N-enriched biochar, 0–30 cm soil labile Po concentration was positively related to leaf concentration of nucleic acid P, 0–15 cm soil moderately labile Pi concentration was positively related to leaf concentration of inorganic P and nucleic acid P. Thus, this study provides evidence that N-enriched biochar increase the soil P-availability of labile and moderately labile P that in turn improved rice plants P use efficiency. | |||||
50. 题目: Grassland biodiversity and ecosystem functions benefit more from cattle than sheep in mixed grazing: A meta-analysis Grasslands have been widely grazed for livestock production by cattle and sheep. However, previous studies have mainly focused on the impacts of single-species grazing on grassland biodiversity and ecosystem functions; the effects of mixed grazing of cattle and sheep remain largely unknown. We conducted a meta-analysis to examine the impacts of mixed grazing and analyzed the relative roles of cattle and sheep on grassland biodiversity and multiple ecosystem functions. Mixed grazing studies mainly originated from Europe, the USA, and China. Generally, cattle and sheep exhibited distinctive impacts on grassland biodiversity and functions in single-species and mixed grazing regimes. Cattle grazing alone increased plant diversity and soil organic carbon content (SOC), while sheep grazing alone had little impact. Compared to single-species grazing, mixed grazing generally increased plant density and richness of insect herbivores and decreased soil nematode richness, but did not alter plant biomass, soil nitrogen, or nematode abundance. Cattle in the mixed grazing regime increased plant diversity, biomasses of forbs and legumes, SOC, and liveweight gains of livestock. The mixed grazing impacts were further regulated by climate conditions, grazing intensity, and grazing duration. Our findings provide compelling evidence that mixed grazing benefits biodiversity, soil carbon sequestration, livestock production, and community structure of grasslands, and cattle are more influential than sheep in creating the benefits of mixed grazing for sustainable management of grasslands. | |||||
51. 题目: Superefficient separation of Th(IV) and U(VI) by lignin-derived magnetic biochar via competitive adsorption mechanism Thorium (Th) and uranium (U) separation remains a huge challenge due to their high similarity in chemical behavior. In this study, lignin-derived magnetic biochar (AL-Fe/BC), which can provide functional sites for adsorbing Th(IV) and U(VI), was synthesized for the selective extraction of Th(IV) from the binary U(VI)-Th(IV) matrix. Characterizations results confirm the successful zero-valent iron loading, and the AL-Fe/BC exhibited a developed polyporous structure, high surface area, stable crystallinity, high defects degree, and advantageous magnetic feature of expedient recovery from water without energy consumption. The optimist AL-Fe/BC-800 showed an outstanding adsorption capacity with a maximal Th(IV) uptake of 2000 mg/g, and a small absorption of 3 mg/g of U(VI) (Th(IV) = 180 mg/L, U(VI) = 20 mg/L, AL-Fe/BC-800 = 0.05 g/L). Moreover, the separation factor of Th(IV) from the Th(IV)-U(VI) matrix reached 90000 even concomitant with high a concentration of co-existing ions. The active adsorption sites on AL-Fe/BC-800, such as COOH, C-OH, C=O, pyridinic N, graphitic N, and pyrrolic N, exhibited a stronger binding affinity with Th(IV) than U(VI), achieving selective Th(IV) adsorption via a chemisorption-related process on the basis of competitive adsorption. In summary, AL-Fe/BC-800 is a potential adsorbent in industrial application for the superefficient separation of Th(IV) and U(VI) with high-performance magnetic recovery, promoting the sustainable development of nuclear industry, especially considering the necessary development of Th(IV) fuel. | |||||
52. 题目: Negative responses of terrestrial nitrogen fixation to nitrogen addition weaken across increased soil organic carbon levels The traditional view holds that biological nitrogen (N) fixation is energetically expensive and thus, facultative N fixers reduce N fixation rates while obligate N fixers are excluded by non-N fixers as soil N becomes rich. This view, however, contradicts the phenomenon that N fixation does not decline in many terrestrial ecosystems under N enrichment. To address this paradoxical phenomenon, we conducted a meta-analysis of N fixation and diazotroph (N-fixing microorganism) community structure in response to N addition across terrestrial ecosystems. N addition inhibited N fixation, but the inhibitory effect weakened across increased soil organic carbon (SOC) concentrations. The response ratios of N fixation (including free-living, plant-associated, and symbiotic types) to N addition were lower in the ecosystems with low SOC concentrations (<10 mg/g) than in those with medium or high SOC concentrations (10–20 and > 20 mg/g, respectively). The negative N-addition effects on diazotroph abundance and diversity also weakened across increased SOC levels. Among the climatic and soil factors, SOC was the most important predictor regarding the responses of N fixation and diazotroph community structure to N addition. Overall, our study reveals the role of SOC in affecting the responses of N fixation to N addition, which helps understand the relationships of biological N fixation and N enrichment as well as the mechanisms of terrestrial C and N coupling. | |||||
53. 题目: In situ reductive dehalogenation of groundwater driven by innovative organic carbon source materials: Insights into halide-respiratory electron transport chains In situ bioremediation using organohalide-respiring bacteria (OHRB) is a prospective method for the removal of persistent halogenated organic pollutants from groundwater, as OHRB can utilize H2 or organic compounds produced by carbon source materials as electron donors for cell growth through organohalide respiration. However, few previous studies have determined the suitability of different carbon source materials to the metabolic mechanism of reductive dehalogenation from the perspective of electron transfer. The focus of this critical review was to reveal the interactions and relationships between carbon source materials and functional microbes, in terms of the electron transfer mechanism. Furthermore, this review illustrates some innovative strategies that have used the physiological characteristics of OHRB to guide the optimization of carbon source materials, improving the abundance of indigenous dehalogenated bacteria and enhancing electron transfer efficiency. Finally, it is proposed that future research should combine multi-omics analysis with machine learning to guide the design of effective carbon source materials and optimize current dehalogenation bioremediation strategies to reduce the cost and footprint of practical groundwater bioremediation applications. | |||||
54. 题目: Riverine and submarine groundwater nutrients fuel high primary production in a tropical bay River discharge has long been recognized as a major source of nutrients supporting high primary production (PP) in Bandon Bay, while submarine groundwater discharge (SGD) and atmospheric deposition have largely been overlooked. In this study, we evaluated contributions of nutrients via river, SGD and atmospheric deposition, and their roles on PP in the bay. Contribution of nutrients from the three sources during different time of the year was estimated. Nutrients supply from Tapi-Phumduang River accounted for two-fold the amount from SGD while very little supply was from atmospheric deposition. Significant seasonal difference in silicate and dissolved inorganic nitrogen were observed in river water. Dissolved phosphorous in river water was mainly (80 % to 90 %) of DOP in both seasons. For the bay water, DIP in wet season was two-fold higher than in dry season while dissolved organic phosphorus (DOP) was only one half of those measured in dry season. In SGD, dissolved nitrogen was mostly inorganic (with 99 % as NH4+), while dissolved phosphorous was predominantly (DOP). In general, Tapi River is the most important source of nitrogen (NO3−, NO2−, and DON), contributing >70 % of all considered sources, especially in wet season, while SGD is a major source for DSi, NH4+ and phosphorus, contributing 50 % to 90 % of all considered sources. To this end, Tapi River and SGD deliver a large quantity of nutrients and support high PP in the bay (337 to 553 mg-C m−2 day−1). | |||||
55. 题目: Radiocarbon constraints on carbon release from the Antarctic ice sheet into the Amundsen Sea Embayment | |||||
56. 题目: Enhanced in-situ sludge reduction of the side-stream process via employing micro-aerobic approach in both mainstream and side-stream Side-stream reactor (SSR), as an in-situ sludge reduction process with high sludge reduction efficiency (SRE) and less negative impact on effluent, has been widely researched. In order to reduce cost and promote large-scale application, the anaerobic/anoxic/micro-aerobic/oxic bioreactor coupled with micro-aerobic SSR (AAMOM) was used to investigate nutrient removal and SRE under short hydraulic retention time (HRT) of SSR. When HRT of SSR was 4h, AAMOM system achieved 30.41% SRE, while maintaining carbon and nitrogen removal efficiency. Micro-aerobic in mainstream accelerated the hydrolysis of particulate organic matter (POM) and promoted denitrification. Micro-aerobic in side-stream increased cell lysis and ATP dissipation, thus increasing SRE. Microbial community structure indicated that the cooperative interactions among hydrolytic, slow growing, predatory and fermentation bacteria played key roles in improving SRE. This study confirmed that SSR coupled micro-aerobic was a promising and practical process, which could benefit nitrogen removal and sludge reduction in municipal wastewater treatment plants. | |||||
57. 题目: Efficient removal of phytochrome using rice straw-derived biochar: Adsorption performance, mechanisms, and practical applications Rice straw derived biochar was fabricated and applied as a purification agent. The adsorption kinetics, isotherms, and thermodynamics for adsorbates were determined using the biochar. Adsorption kinetics and isotherms were best fitted by the pseudo-second order and Langmuir models. Biochar could effectively remove chlorophyll in 9 different solutions. Biochar was employed as a clean-up reagent for 149 pesticides detection, which revealed that biochar had a higher phytochrome removal capacity than graphitized carbon black and 123 pesticides had satisfactory recovery values. The biochar was prepared into a sample pad by electrospinning and was then used for online sample clean-up in a test strip, and it showed high ability of removing phytochrome and improving detection sensitivity. Thus, biochar could be applied as a purification agent to remove pigmentation, making it a promising candidate not only for sample pretreatment but also in the fields of food, agriculture and environment. | |||||
58. 题目: How biotic, abiotic, and functional variables drive belowground soil carbon stocks along stress gradient in the Sundarbans Mangrove Forest? Mangrove forests, some of the most carbon-dense ecosystems on Earth, play an important role in climate change mitigation through storing carbon in the soil. However, increasing anthropogenic pressures and sea level rise are likely to alter mangrove forest structure and functions, including the major source of carbon in mangrove ecosystems — below-ground soil carbon stocks (BSCS). Although estimating soil carbon stocks has been a popular practice in the mangroves, but poorly understood the (I) the linkage between BSCS and key ecosystem drivers (i.e., biotic, abiotic, and functional) and in (II) determining the pathways of how BSCS and multiple forest variables interact along stress gradients. This lack of understanding limits our ability to predict ecosystem carbon dynamics under future changes in climate. Here, we aimed to understand how abiotic factors (such as salinity, canopy gap fraction, nutrients, and soil pH), biotic factors (e.g., structural parameters, canopy packing, and leaf area index, LAI), and forest functional variables (e.g., growth and aboveground biomass stocks, AGB) affect BSCS (i.e., soil organic carbon, SOC, and root carbon, RC) using spatiotemporal data collected from the Sundarbans Mangrove Forest (SMF) in Bangladesh. We observed that BSCS decreased significantly with increasing salinity (e.g., from 70.6 Mg C ha−1 in the low-saline zone to 44.6 Mg C ha−1 in the high-saline zone). In contrast, the availability of several macronutrients (such as nitrogen, phosphorous, and potassium), LAI, species diversity, AGB, and growth showed a significant positive effect on SOC and RC. Stand properties, including tree height, basal area, density, canopy packing, and structural diversity, had a non-significant but positive impact on RC, while tree height and basal area significantly influenced SOC. Pathway analysis showed that salinity affects BSCS variability directly and indirectly by regulating stand structure and restricting nutrients and forest functions, although basal area, nutrients, and LAI directly enhance RC stocks. Our results indicate that an increase in nutrient content, canopy density, species diversity, and leaf area index can enhance BSCS, as they improve forest functions and contribute to a better understanding of the underlying mechanisms. | |||||
59. 题目: Enhanced removal of organic matter from oxygen-pressure leaching solution by modified anode slime Organic matter has become a typical harmful impurity, posing a serious problem and catastrophic effects in the hydrometallurgical extraction of zinc. The highly efficient and inexpensive method for the removal of organics from the leaching solution is of great practical significance for the efficient operation of zinc hydrometallurgy. For this reason, the removal of organic matter from oxygen-pressure leaching solution using modified anode slime was investigated by TOC analysis, FTIR spectroscopy, XRD, GCMS, and other characterization methods, and its mechanism was also discussed. The results show that the removal of organic matter using anode slime modified with sulfuric acid was significantly improved, and the removal of TOC reached 57.83% for anode slime modified at a temperature of 80 °C with a ratio of sulfuric acid to anode slime of 14 mL/100 g, which was more than 2.7 times that of untreated anode slime. The good removal effect of organic matter using the modified anode slime could be attributed to the transformation of inert α-MnO2 to active MnOOH by concentrated sulfuric acid-mediated modification. It was also found that the acid–solid ratio and temperature exhibited a significant effect on the modification of anode slime. The XPS analysis results of Mn 2p, Mn 3s, and O 1s, combined with the XRD patterns of the modified products indicated that the modification of anode slime led to the conversion of MnO2 in anode slime to MnOOH in the presence of H2SO4. However, MnO2 was further converted into high crystallinity MnOOH, even MnSO4 when the temperature exceeded 80 °C or the acid–solid ratio exceeded 18 mL/100 g, resulting in the decreased degradation performance for organic matter. The characterization results of FTIR spectroscopy and GCMS show that modified anode slime does not exhibit a degradation effect on all types of organic substances in leaching solution; however, it is very effective for some alcohols, olefins, and esters. | |||||
60. 题目: Study on the potential of sludge-derived humic acid as energy storage material As one of the main methods for sludge treatment, recovery of renewable biogas energy by anaerobic digestion (AD) is a promising strategy to deal with the conflict between carbon neutralization and sharply increase of sewage sludge. Humic acid (HA) in sludge is a major inhibitor of biogas yields and needs to be removed or pretreated. However, as the graphene oxide-like material, HA is an ideal precursor for the preparation of energy storage materials with high performance. Based on that, this study i) proposes the extraction and utilization of HA in sludge, ii) discusses the feasibility of HA-based materials after thermal reduction as electrodes for supercapacitor, and iii) investigates the factors with positive influences on the structure and electrochemical performance. It reveals that, with a synergistic effect of purification and activation at a low mass ratio, the HA-based material exhibits superior capacitive performance with the highest specific capacitance of 186.7 F/g (at 0.05 A/g), as well as excellent rate capability and cycling stability. Sludge is verified a cheaper and more abundant precursor resource of HA for energy storage application. The results of this study are expected to provide a new green, energy-efficiency and sustainability way for sludge treatment, which has the double benefits: efficient conversion and capture of bio-energy during AD process, and high value-added utilization of HA for supercapacitor. | |||||
