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12781. 题目: Evaluation of integrated biochar with bacterial consortium on gaseous emissions mitigation and nutrients sequestration during pig manure composting
文章编号: N19072603
期刊: Bioresource Technology
作者: Yumin Duan, Sanjeev Kumar Awasthi, Tao Liu, Zengqiang Zhang, Mukesh Kumar Awasthi
更新时间: 2019-07-26
摘要: This study focused on evaluate the effectiveness of biochar alone compare integrated with bacterial consortium amendment on the gaseous emissions mitigation as well as carbon and nitrogen sequestration during pig manure composting. Six additive treatments were performed based on uniform mixing pig manure with wheat straw[bacterial consortium (T2), 12%wood biochar (T3), 12%wood biochar + bacterial consortium (T4), 12%wheat straw biochar (T5), 12%wheat straw biochar+ bacterial consortium (T6), while T1 without any additive]. The results obviously indicated that integrated use of biochar and bacterial consortium could remarkably relieved gaseous emissions, improved carbon and nitrogen conservation as well as accelerated maturity of composting. Notably the optimum combination was existed in T6 owing to lowest nutrient losses (nitrogen and carbon losses were 9.91 g/kg and 189.54 g/kg) and gas emissions (30.16 g/kg) as well as supreme maturity (germination index > 100%); it’s an economic-practical and environmental protection novel disposal approach for solid waste.
图文摘要:

12782. 题目: Perchlorate behavior in the context of black carbon and metal cogeneration following fireworks emission at Oak Lake, Lincoln, Nebraska, USA
文章编号: N19072602
期刊: Environmental Pollution
作者: Manish Kumar, Daniel D. Snow, Yusong Li, Patrick J. Shea
更新时间: 2019-07-26
摘要: The imprints of fireworks displays on the adjacent water body were investigated from the perspective of cogeneration of black carbon, metals and perchlorate (ClO4). In particular, the mixing and dissipation of ClO4 were studied at Oak Lake, Lincoln, Nebraska, following fireworks displays in 2015 and 2016. Following the display, ClO4 concentration in the water increased up to 4.3 μg/L and 4.0 μg/L in 2015 and 2016, respectively. A first-order model generally provided a good fit to the measured perchlorate concentrations from which the rate of dissipation was estimated as 0.07 d−1 in 2015 and 0.43 d−1 in 2016. SEM images show imprints of soot and metal particles in aerosol samples. EDS analysis of the lake sediment confirmed the presence of Si, K, Ca, Zn and Ba, most of which are components of fireworks. The δ13C range of −7.55‰ to −9.19‰ in the lake water system closely resembles fire-generated carbon. Cogeneration of black carbon and metal with perchlorate was established, indicating that ClO4 is an excellent marker of fireworks or a burning event over all other analyzed parameters. Future microcosmic, aggregation and column-based transport studies on black carbon in the presence of perchlorate and metals under different environmental conditions will help in developing transport and fate models for perchlorate and black carbon particles.
图文摘要:

12783. 题目: Strategies for the efficient estimation of soil organic carbon at the field scale with vis-NIR spectroscopy: Spectral libraries and spiking vs. local calibrations
文章编号: N19072601
期刊: Geoderma
作者: Michael Seidel, Christopher Hutengs, Bernard Ludwig, Sören Thiele-Bruhn, Michael Vohland
更新时间: 2019-07-26
摘要: Soil spectroscopy in the visible-to-near-infrared (vis-NIR) range is a cost-effective alternative analysis technique to determine soil organic carbon (SOC). The development and provision of large-scale soil spectral libraries (SSLs) further facilitates the application of vis-NIR spectroscopy for the rapid assessment of SOC. However, optimal strategies to apply SOC calibrations from SSLs to independent field sites have yet to be established.We tested the predictive ability of SOC calibrations based on three external SSLs at the national, regional and field scale by applying them to two field sites in Germany. The national-scale SSL was comprised as a subset of the European LUCAS 2009 topsoil database. This subset was further classified into a randomly selected subset and target site-specific subsets based on similarity of spectral characteristics and soil parent material. A regional- and a field-scale legacy dataset were additionally used to predict SOC at the two field sites and to compare the results with the performance of the LUCAS based models. SSL-based predictive models adapted to the characteristics of the target sites by means of spiking were evaluated against purely local calibrations.Models calibrated with spectra from the LUCAS library and the regional-scale dataset predicted the SOC contents of the target field sites generally poorly (0.45 ≤ RPD ≤ 2.08), largely as a result of biased estimates. Spiking the models with only a few (~15) samples from the target sites reduced prediction bias drastically and thus yielded markedly improved SOC estimates for nearly all redeveloped models (1.30 ≤ RPD ≤ 3.69). Spiking the models based on the field-scale SSL with 15 samples produced better results than the spiked larger national and regional calibration sets, with RPD values of 5.66 and 4.14 for both target sites.Our results suggest that universal calibrations based exclusively on library spectra of larger scale are insufficient for accurate SOC assessments at the local scale even with pedogenetically or spectrally adapted calibration subsets. Spiking the vis-NIR models based on SSLs with a small number of target site samples allows a successful transfer of SOC calibrations, but does not necessarily yield more accurate predictions than local models developed exclusively with the spiking samples or calibrations based on field-scale SSL with similar characteristics, which may be preferable for model development if available.

12784. 题目: Deep Sulfate-Methane-Transition and sediment diagenesis in the Gulf of Alaska (IODP Site U1417)
文章编号: N19072510
期刊: Marine Geology
作者: Mark Zindorf, Christian März, Thomas Wagner, Sean P.S. Gulick, Harald Strauss, Jeff Benowitz, John Jaeger, Bernhard Schnetger, Laurel Childress, Leah LeVay, Cees van der Land, Michelle La Rosa
更新时间: 2019-07-25
摘要: Sediment samples from the Gulf of Alaska (GOA, IODP Expedition 341, Site U1417) have been analyzed to understand present and past diagenetic processes that overprint the primary sediment composition. No Sulfate-Methane Transition Zone (SMTZ) was observed at the zone of sulfate depletion, but a >200 m thick sulfate- and methane-free sediment interval occurred between the depth of sulfate depletion (~200 m) and the onset of methanogenesis (~440 m). We suggest that this apparent gap in biogeochemical processing of organic matter is caused by anaerobic oxidation of methane fueled by sulfate which is released during dissolution of barites at the upper boundary of the methane rich layer. Beneath the methanogenic zone, at ~650 m depth, pore-water sulfate concentrations increase again, indicating sulfate supply from greater depth feeding into a deep, inverse SMTZ. A likely explanation for the availability of sulfate in the deep sub-seafloor at U1417 is the existence of a deep aquifer related to plate bending fractures, which actively transports sulfate-rich water to, and potentially along, the interface between sediments and oceanic crust. Such inverse diagenetic zonations have been previously observed in marine sediments, but have not yet been linked to subduction-related plate bending. With the discovery of a deep inverse SMTZ in an intra-oceanic plate setting and the blocking of upward methane diffusion by sulfate released from authigenic barite dissolution, Site U1417 provides new insights into sub-seafloor pore-fluid and gas dynamics, and their implications for global element cycling and the deep biosphere.

12785. 题目: Rigorous Physicochemical Framework for Metal Ion Binding by Aqueous Nanoparticulate Humic Substances: Implications for Speciation Modeling by the NICA-Donnan and WHAM Codes
文章编号: N19072509
期刊: Environmental Science & Technology
作者: Raewyn M. Town, Herman P. van Leeuwen, Jérôme F. L. Duval
更新时间: 2019-07-25
摘要: Latest knowledge on the reactivity of charged nanoparticulate complexants toward aqueous metal ions is discussed in mechanistic detail. We present a rigorous generic description of electrostatic and chemical contributions to metal ion binding by nanoparticulate complexants, and their dependence on particle size, particle type (i.e., reactive sites distributed within the particle body or confined to the surface), ionic strength of the aqueous medium, and the nature of the metal ion. For the example case of soft environmental particles such as fulvic and humic acids, practical strategies are delineated for determining intraparticulate metal ion speciation, and for evaluating intrinsic chemical binding affinities and heterogeneity. The results are compared with those obtained by popular codes for equilibrium speciation modeling (namely NICA-Donnan and WHAM). Physicochemical analysis of the discrepancies generated by these codes reveals the a priori hypotheses adopted therein and the inappropriateness of some of their key parameters. The significance of the characteristic time scales governing the formation and dissociation rates of metal–nanoparticle complexes in defining the relaxation properties and the complete equilibration of the metal–nanoparticulate complex dispersion is described. The dynamic features of nanoparticulate complexes are also discussed in the context of predictions of the labilities and bioavailabilities of the metal species.

12786. 题目: Mixed carbonate-siliciclastic MICROFACIES from PERMIAN deposits of western Gondwana: Evidence of gradual marine to continental transition or episodes of marine transgression?
文章编号: N19072508
期刊: Sedimentary Geology
作者: Christiano Ng, Cristina Silveira Vega, Maria da Saudade Araujo Santos Maranhão
更新时间: 2019-07-25
摘要: At the end of the Paleozoic, several intracratonic basins developed in Gondwana, including the Paraná Basin in Western Gondwana. Permian sedimentary units include the Passa Dois Group, which encompasses four formations: the Irati, Serra Alta, Teresina, and Rio do Rasto, and represents a transition from marine to continental depositional environments. Its strata correlate extensively, from Argentina to South Africa, and the Irati and Teresina formations in particular present mixed carbonate-siliciclastic successions. This interval has been speculated to have formed under several different paleoenvironmental scenarios; however, Permian Gondwana basin microfacies, with no open sea influence, have rarely been studied. In addition, in these basins there is a scarcity of micropaleontological studies and geochronological calibration, besides an absence of marine index fossils. In view of this, a comprehensive microfacies study for the unit is developed, with a large and representative surface and subsurface sample analysis of the Passa Dois Group, divided into three large geographic domains: north, central, and south of the Paraná Basin, Brazil. Thin sections distributed among the four units were analyzed with an emphasis on carbonate layers where the microfossils have a better chance to be recognized. The data were interpreted within a revised biochronostratigraphic framework and integrated with bivalves, macroflora, palynology, conchostracans, and vertebrates biozones. Microfacies analysis resulted in the recognition of 13 microfacies: four siliciclastic, eight carbonate, and one siliceous (chert). We observed a predominance of fine siliciclastic microfacies, rich in organic matter, in the Southern Domain; rudaceous carbonate microfacies in the Central Domain, with diverse allochemicals and the greater diversity of bioclasts; and an increase on siliciclastic sediments influx in the Northern Domain of the basin, where only the Irati and Teresina formations occur. A shortage of microfossils was observed in the South Domain, where the carbonate microfacies are less varied than those to the north. In the Central Domain, coarse-grained carbonates are present. Bivalves, ostracods, and sponge spicules are the main bioclasts on rudstones and grainstones from the Irati and Teresina formations, and have been interpreted as allochthonous to parautochthonous. The association of detrital and authigenic glauconite to bioaccumulations of sponge spicules is interpreted as episodes of marine transgression.

12787. 题目: Ammonia‐oxidizing archaea release a suite of organic compounds potentially fueling prokaryotic heterotrophy in the ocean
文章编号: N19072507
期刊: Environmental Microbiology
作者: Barbara Bayer, Roberta L. Hansman, Meriel J. Bittner, Beatriz E. Noriega‐Ortega, Jutta Niggemann, Thorsten Dittmar, Gerhard J. Herndl
更新时间: 2019-07-25
摘要: Ammonia‐oxidizing archaea (AOA) constitute a considerable fraction of microbial biomass in the global ocean, comprising 20‐40% of the ocean's prokaryotic plankton. However, it remains enigmatic to what extent these chemolithoautotrophic archaea release dissolved organic carbon (DOC). A combination of targeted and untargeted metabolomics was used to characterize the exometabolomes of three model AOA strains of the Nitrosopumilus genus. Our results indicate that marine AOA exude a suite of organic compounds with potentially varying reactivities, dominated by nitrogen‐containing compounds. A significant fraction of the released DOM consists of labile compounds, which typically limit prokaryotic heterotrophic activity in open ocean waters, including amino acids, thymidine, and B vitamins. Amino acid release rates corresponded with ammonia oxidation activity and the three Nitrosopumilus strains predominantly released hydrophobic amino acids, potentially as a result of passive diffusion. Despite the low contribution of DOC released by AOA (~0.08‐1.05%) to the heterotrophic prokaryotic carbon demand, the release of physiologically relevant metabolites could be crucial for microbes that are auxotrophic for some of these compounds, including members of the globally abundant and ubiquitous SAR11 clade. This article is protected by copyright. All rights reserved.

12788. 题目: Coupled steel slag and biochar amendment correlated with higher methanotrophic abundance and lower CH4 emission in subtropical paddies
文章编号: N19072506
期刊: Environmental Geochemistry and Health
作者: Miaoying Wang, Chun Wang, Xingfu Lan, Abbas Ali Abid, Xuping Xu, Ankit Singla, Jordi Sardans, Joan Llusià, Josep Peñuelas, Weiqi Wang
更新时间: 2019-07-25
摘要: Aerobic methanotrophs in paddies serve as methane (CH4) filters and thereby reduce CH4 emissions. Amending soil with waste products can mitigate CH4 emissions in crops, but little is known about the impacts of amendments with steel slag and biochar on the populations and activities of aerobic methanotrophs in rice cropland. We used real-time quantitative PCR detecting system and high-throughput sequencing to determine the effects of slag and biochar amendments on CH4 emission, abundance, and community structure of methanotrophs, and the relationships between soil properties and the abundance and community composition of methanotrophs during the rice growing season in both early and late paddies. Soil salinity and pH were significantly higher for an amendment with both slag and biochar than the control in both the early and late paddies, and pH was significantly higher for a slag amendment in the late paddy. Cumulative CH4 emission was lower for the slag and slag + biochar amendments than the control in early paddy by—34.1%. Methanotrophic abundance was three- and sixfold higher for the slag + biochar amendment than the control in the early and late paddies (p < 0.05), respectively. The abundance of different groups of methanotrophs varied among the treatments. The relative abundance of Methylosarcina was higher for the slag amendment than the control, and the relative abundance of Methylomonas was lower for biochar, and slag + biochar amendments than the control. The relative abundance of Methylocystis was higher for the slag and slag + biochar amendments than the control in the early paddy, and the relative abundance of Methylocystis was higher for the slag, biochar, and slag + biochar amendments in the late paddy. Univariate and multivariate analyses indicated that the higher abundance of methanotrophic bacteria for the slag and slag + biochar amendments was correlated with soil pH, salinity, soil organic carbon, and C/N ratio, and the relative abundances of Methylocystis, Methylomonas, and Methylosarcina were associated with the effective mitigation of CH4 emission in the paddies. A discriminant general analysis indicated that the total population of methanotrophs was larger for the slag + biochar amendment than the control, and that this effect was only weakly correlated with changes in the soil properties, demonstrating that this effect on the size and species composition of methanotrophic soil populations was mostly associated with a direct effect of the slag + biochar amendment.

12789. 题目: PLANT RESTORATION LEADS TO DIVERGENT SEQUESTRATION OF SOIL CARBON AND NITROGEN IN DIFFERENT FRACTIONS IN AN ARID DESERT REGION
文章编号: N19072505
期刊: Land Degradation & Development
作者: Xiao‐hong Jia, Yuan‐shou Li, Bo Wu, Qi Lu, Xin‐rong Li
更新时间: 2019-07-25
摘要: Soil organic carbon (OC) and nitrogen (N) associated with particle size fractions can be used as sensitive indicators to evaluate impacts of land use change on soil total OC (TOC) and total N (TN) pools. Aeolian sandy soils were collected from seven sites in the Tengger Desert, representing a 56‐year chronosequence of plant restoration at decadal intervals in an arid desert region. Bulk soils were separated into silt+clay (<53 μm), fine sand (53–100 μm), and coarse sand (>100 μm) fractions. TOC and TN concentrations of bulk soil and their levels associated with particle size fractions were analyzed. Results showed that plant restoration promoted C and N sequestration in both topsoil and subsoil layers over time, as indicated by elevated levels of OC and N associated with silt+clay and sand fractions. TOC and TN concentrations of 56‐year restored topsoil respectively increased by 31‐ and 43‐fold compared with the control (moving dunes); corresponding levels associated with silt+clay or coarse sand fraction respectively increased by more than 30‐ and 20‐fold, while less than 15‐fold increases were found in fine sand fraction. In the early stages of plant restoration, both C and N sequestration primarily resulted from finer particle size fractions. In the later stages, increased C sequestration was principally derived from coarse sand fraction, while N sequestration was mainly derived from silt+clay fraction. The results highlight that plant restoration stage and soil textural change are key factors leading to divergent soil C and N sequestration in the arid desert region.

12790. 题目: Response of bacterial communities in coastal mudflat saline soil to sewage sludge amendment
文章编号: N19072504
期刊: Applied Soil Ecology
作者: Yanchao Bai, Lijuan Mei, Wengang Zuo, Yang Zhang, Chuanhui Gu, Yuhua Shan, Jian Hu, Qigen Dai
更新时间: 2019-07-25
摘要: Microbial communities are of great importance in the development of saline soil fertility in coastal mudflats. However, the effects of sewage sludge use on the microbiome in saline soils of mudflats are unknown. This study aimed to investigate the response profile of bacterial communities in mudflat saline soil to sewage sludge amendment (SSA). Mudflat soil was treated once at the rates of 0, 30, 75, and 150 ton sewage sludge per hectare. Ryegrass, Sesbania, and Maize were successively planted and tilled. Approximately 3 years after the initial amendment, the Illumina Miseq sequencing of the 16S rRNA gene was performed to study bacterial community of mudflat soil. The results indicated that SSA significantly changed the mudflat saline soil bacterial community. A total of 37 phyla were found, dominated by Bacteroidetes, Proteobacteria, Chloroflexi, Actinobacteria, Acidobacteria, Planctomycetes, and Firmicutes. The SSA resulted in an increase in the comparable richness of Chloroflexi, Planctomycetes and Firmicutes, as well as a decrease in Proteobacteria. The canonical correspondence analysis indicated that the bacterial community structure was negatively affected by alkalinity or salinity, while positively affected by soil organic matter, and the N and P concentration in the saline soil. The bacterial community composition in the saline soil was altered by SSA. Lower salinity and alkalinity, and higher organic matter and nutrients favored microhabitats more suitable for bacteria.

12791. 题目: Water extractable organic matter (WEOM) as an indicator of granular activated carbon (GAC) bed life and water quality outcomes in drinking water treatment
文章编号: N19072503
期刊: Environmental Science: Water Research & Technology
作者: Jonathan Peter Ritson, Nigel Graham
更新时间: 2019-07-25
摘要: Granular activated carbon (GAC) is often used in drinking water treatment to remove dissolved organic carbon (DOC), taste and odour compounds, and organic micro-pollutants. As these chemicals are adsorbed onto the GAC surface, the area available for further adsorption decrease, meaning that the removal of target compounds decreases over time. Ascertaining the correct point to regenerate the GAC is a critical parameter in terms of both water quality performance and operational expenditure for the water company. Using a test case of a UK water treatment works with five GAC beds of varying age we show that current practices of using time-in-use are ineffective for optimal removal of DOC and disinfection by-product precursors. Our data show that assessment of the water extractable organic matter (WEOM) adsorbed onto the GAC can give an accurate indicator of both DOC removal (adjusted R2 =0.985, p=0.001, n=5) and reduction in trihalomethane formation (adjusted R2 =0.970, p=0.001, n=5). These results suggest that simple methods using equipment commonly available at treatment works could be adopted for rapid assessment of remaining GAC bed life.

12792. 题目: Introducing nitrogen-fixing tree species and mixing with Pinus massoniana alters and evenly distributes various chemical compositions of soil organic carbon in a planted forest in southern China
文章编号: N19072502
期刊: Forest Ecology and Management
作者: Hui Wang, Shirong Liu, Zhanchao Song, Yujing Yang, Jingxin Wang, Yeming You, Xiao Zhang, Zuomin Shi, You Nong, Angang Ming, Lihua Lu, Daoxiong Cai
更新时间: 2019-07-25
摘要: There are potential effects of converting a planted-forest type from conifer to broadleaf or mixed-species on soil organic carbon (SOC) chemical composition, and the quantity and distribution of various chemical compositions of SOC remain uncertain. An afforestation experiment with different tree species (Pinus massoniana, Erythrophleum fordii [N-fixing species], and mixed P. massoniana and E. fordii) was conducted in clear-cut sites of P. massoniana-planted forests in a subtropical region. Topsoil organic C quality and microbial diversity were assessed after eight years of afforestation. Referring to the species diversity index in the community, Pielou’s evenness index was used for estimating the evenness of distribution of various organic C compositions in the total organic C of soil, litter, and fine roots. The proportions of alkyl C and carbonyl C in SOC, as well as the alkyl C/O-alkyl C (A/O-A) ratios and the distributed evenness of the four main SOC chemical compositions were higher in the monospecific E. fordii and mixed-species-planted forests than in the monospecific P. massoniana-planted forest. Positive relationships of the A/O-A ratio and the evenness of distribution of various SOC chemical compositions in the litter as well as fine root C quality were observed. Microbial biomass C was positively correlated with the labile SOC (O-alkyl C). Multivariate analysis showed that the fine roots had a closer correlation with the chemical composition of SOC than the litter. These results highlight that introducing native N-fixing broadleaf tree species and mixing N-fixing species into conifer forests probably enhances the SOC chemical stability. It also minimizes the risk of C decomposition posed by any one soil organic matter (SOM) constituent having a huge impact during climate change through increasing the proportion of recalcitrant C components and even distribution of various SOM chemical compositions.

12793. 题目: Selective preservation of pyrogenic carbon across soil organic matter fractions and its influence on calculations of carbon mean residence times
文章编号: N19072501
期刊: Geoderma
作者: J.M. Lavallee, R.T. Conant, M.L. Haddix, R.F. Follett, M.I. Bird, E.A. Paul
更新时间: 2019-07-25
摘要: The long-standing perspective that recalcitrance of soil organic carbon (SOC) controls its stability and persistence has shifted to one in which physical inaccessibility of SOC to microorganisms plays a predominant role. This paradigm shift has been facilitated by analytical techniques that isolate SOC into physical fractions protected from decomposers by different mechanisms. The correlation between these fractions and SOC age has reinforced the emphasis of SOC inaccessibility. Pyrogenic C (PyC; also called charcoal or black carbon), which has been thermally altered by fire, is known to contain highly recalcitrant components that decompose very slowly and could represent an exception to this paradigm shift. We employed hydrogen pyrolysis to quantify the contribution of PyC to total SOC across soil fractions from three long-term agricultural experiments with land use conversions that caused reductions in SOC. We show that all soil fractions contain PyC and up to one-fifth of SOC in soil fractions considered to have low accessibility is comprised of PyC. Regardless of the soil fraction in which it was located, PyC was relatively unaffected by land use conversion compared to biogenic C (organic C not altered by fire), which suggests that selective preservation, rather than physical protection, is the dominant mechanism limiting PyC decomposition in these sites. We accounted for PyC in calculations of C mean residence times (MRTs) using differences in stable C isotope ratios between PyC and SOC. Though results varied by site and soil fraction, MRTs for biogenic C were generally shorter than for total SOC. Based on these results, PyC decomposition is controlled by a different mechanism than biogenic C, and this should be considered in studies of soil C dynamics. In addition, methods based on physical fractionation alone may place too great an emphasis on the role of inaccessibility for long-term SOC persistence.

12794. 题目: Spring flood induced shifts in Fe speciation and fate at increased salinity
文章编号: N19072419
期刊: Applied Geochemistry
作者: S.D. Herzog, S. Conrad, J. Ingri, P. Persson, E.S. Kritzberg
更新时间: 2019-07-24
摘要: Rivers have traditionally been viewed as negligible sources of iron (Fe) to marine waters, as most Fe gets lost during estuarine mixing. However, recent findings demonstrate that Fe from boreal rivers display a higher resistance towards salinity-induced aggregation, presumably due to stabilizing interactions with organic matter. Previous studies have shown that Fe (oxy)hydroxides are selectively removed by aggregation processes, and that organic Fe complexes are less affected by increasing salinity. It has been further proposed that Fe speciation varies in response to seasonal differences in hydrology. In this study X-ray absorption spectroscopy was used to determine the temporal variation in Fe speciation and the connection to Fe stability in response to increasing salinity in two boreal rivers (Kalix and Råne River), with the purpose to better understand the fate of riverine Fe export. Sampling was done from winter pre-flood, over the spring flood, to post-flood conditions (early April until mid June). In addition, parallel analyses for Fe speciation and isotope composition (δ56Fe relative to IRMM-14) were made on river samples, as well as salinity-induced aggregates and the fraction remaining in suspension, with the main objective to test if δ56Fe reflect the speciation of Fe.The contribution of organically complexed Fe increased during spring flood compared to the pre- and post-flood, as did Fe transport capacity. However, since Fe (oxy)hydroxides were dominating throughout the sampling period, the seasonal variability was small. Interestingly, salinity-induced aggregation experiments revealed that Fe (oxy)hydroxide, which dominated aggregates, displayed lower δ56Fe than in the river samples Fe, while organic Fe complexes in suspension had higher δ56Fe values. The seasonal variability in Fe isotope signature could not be simply linked to Fe speciation, but was probably also influenced by variation in source areas of Fe and processes along the flow-path that alter both Fe speciation and isotopic composition.
图文摘要:

12795. 题目: Soil productivity drivers in New Zealand planted forests
文章编号: N19072418
期刊: Forest Ecology and Management
作者: P.N. Beets, M.O. Kimberley, L.G. Garrett, T.S.H. Paul, A.L. Matson
更新时间: 2019-07-24
摘要: Soil fertility is one of a number of environmental and biotic drivers of Pinus radiata (D. Don) productivity in New Zealand’s planted forest estate. However, its importance as a driver of productivity at a national scale is uncertain. This paper uses New Zealand’s planted forest inventory plot network, which encompasses a wide range of planted forest environments in New Zealand, to quantify climatic, soil, and biotic drivers of P. radiata productivity. The P. radiata index of site productivity used in this study, the 300 Index, is defined as the mean annual increment in stem volume under bark at age 30 years, of stands growing at a final crop stocking of 300 trees per hectare, and thinned and pruned following a standardised regime. This site productivity index was found to be significantly related to climate (30 year normalised average temperature and rainfall), solar radiation (corrected for slope, horizon and aspect using a digital terrain model), tree health, and soil fertility variables. After adjusting for the effects of solar radiation, temperature and rainfall, site productivity across the New Zealand planted estate was found to be negatively related to the soil C/N ratio and positively related to the size of the soil organic matter pool. The size of the organic matter pool could be represented in the regression model by either the total carbon, total nitrogen, or organic phosphorus concentration of the topsoil. Of these three soil variables, soil total nitrogen was statistically the most significant variable in the model, when analysed in conjunction with the soil C/N ratio. Afforested pastoral farmland previously treated with phosphatic fertilisers to stimulate nitrogen-fixation by leguminous species had soils with a lower C/N ratio and a higher organic matter content. This contributed to an 18% gain in P. radiata productivity compared to land without an agricultural land use history. Having established a relationship between the P. radiata productivity index and climate and soil fertility key drivers, we also consider methods for improving regression model accuracy.

12796. 题目: Soil organic matter characteristics in drained and rewetted peatlands of northern Germany: Chemical and spectroscopic analyses
文章编号: N19072417
期刊: Geoderma
作者: Wakene Negassa, Andre Acksel, Kai-Uwe Eckhardt, Tom Regier, Peter Leinweber
更新时间: 2019-07-24
摘要: Understanding soil organic matter concentration (SOM) and chemistry in different peatlands can help design appropriate management practices for sustainable use of peatland agroecosystems. However, detailed information on characteristics of SOM concentration and chemistry is not available for most peatland agroecosystems in general and in northern Germany in particular. In this study, we investigated the SOM concentration and chemistry of drained and rewetted percolation mires, forest and coastal peatlands. We used simple chemical analysis, pyrolysis field ionization mass spectroscopy (Py-FIMS), and carbon and nitrogen X-ray absorption near-edge structure (XANES) spectroscopy. The total organic carbon (Corg), total nitrogen (N), and total sulfur (S) contents were significantly (P < 0.05) different among the peatlands. The Corg at the surface horizons ranged from 164 to 373 g kg−1, and these values were lower than that of the subsurface horizons of the studied peatlands except for the drained alder carr forest and coastal peatlands. The Py-FIMS indicated that the labile SOM compound classes (carbohydrates, phenols, and lignin monomers, and amino acids, peptides, and amino-sugars) and stable SOM compounds classes (lignin dimers, heterocyclic nitrogen compounds, and nitriles) were abundant at the surface horizons. However, the stable compound classes such as lipids, alkanes, alkenes, fatty acids, n-alkyl esters, and suberin were more abundant at the subsurface horizons than the surface horizons. The carbon K-edge spectra revealed that aromatic C, carboxylic C, O-alkyl, and aliphatic C were the predominant C functional groups, whereas N K edge spectra indicated that the amide group was the predominated N functional group. The SOM concentrations and some compound classes were higher in the rewetted sites of alder carr forest peatland (more carbohydrates, suberin and fatty acids) and of percolation mires (more lignin dimers, lipids and alkylaromatics). The results indicate that the effects of rewetting peatlands on SOM concentration and chemistry depend on peatland type.

12797. 题目: Impact of long-term nitrogen deposition on the response of dune grassland ecosystems to elevated summer ozone
文章编号: N19072416
期刊: Environmental Pollution
作者: Felicity Hayes, Bethan Lloyd, Gina Mills, Laurence Jones, Anthony J. Dore, Edward Carnell, Massimo Vieno, Nancy Dise, Nathalie Fenner
更新时间: 2019-07-24
摘要: Nitrogen deposition and tropospheric ozone are important drivers of vegetation damage, but their interactive effects are poorly understood. This study assessed whether long-term nitrogen deposition altered sensitivity to ozone in a semi-natural vegetation community. Mesocosms were collected from sand dune grassland in the UK along a nitrogen gradient (5–25 kg N/ha/y, including two plots from a long-term experiment), and fumigated for 2.5 months to simulate medium and high ozone exposure. Ozone damage to leaves was quantified for 20 ozone-sensitive species. Soil solution dissolved organic carbon (DOC) and soil extracellular enzymes were measured to investigate secondary effects on soil processes.Mesocosms from sites receiving the highest N deposition showed the least ozone-related leaf damage, while those from the least N-polluted sites were the most damaged by ozone. This was due to differences in community-level sensitivity, rather than species-level impacts. The N-polluted sites contained fewer ozone-sensitive forbs and sedges, and a higher proportion of comparatively ozone-resistant grasses. This difference in the vegetation composition of mesocosms in relation to N deposition conveyed differential resilience to ozone.Mesocosms in the highest ozone treatment showed elevated soil solution DOC with increasing site N deposition. This suggests that, despite showing relatively little leaf damage, the ‘ozone resilient’ vegetation community may still sustain physiological damage through reduced capacity to assimilate photosynthate, with its subsequent loss as DOC through the roots into the soil.We conclude that for dune grassland habitats, the regions of highest risk to ozone exposure are those that have received the lowest level of long-term nitrogen deposition. This highlights the importance of considering community- and ecosystem-scale impacts of pollutants in addition to impacts on individual species. It also underscores the need for protection of ‘clean’ habitats from air pollution and other environmental stressors.
图文摘要:

12798. 题目: Microcystin-LR removal by ion exchange: Investigating multicomponent interactions in natural waters
文章编号: N19072415
期刊: Environmental Pollution
作者: Fuhar Dixit, Benoit Barbeau, Madjid Mohseni
更新时间: 2019-07-24
摘要: Microcystin-LR (MCLR) is the most commonly encountered toxic microcystin variant. MCLR is usually present along with common surface water constituents such as inorganic ions and natural organic matter (NOM) which compete with MCLR for active sites during ion exchange (IX) process. Consequently, development of a multicomponent competitive model is essential for practical IX applications. This is critically important given that the NOM characteristics (charge density and molecular weight distribution) and inorganic ions concentrations are spatially variable and can change seasonally. In the present study, a systematic study was carried out into the multicomponent interactions of IX resin with inorganic ions and NOM during the MCLR removal process. This involved evaluation of MCLR removal in a single component system (i.e., MCLR only), a dual component system (MCLR and one other contaminant such as NOM), and a multiple component system (MCLR with NOM and different inorganic ions present in natural waters). A comprehensive understanding of the dynamic adsorption behavior showed that the experimental data for single component systems agree well with a Freundlich isotherm. For multicomponent interactions, the Equivalent Background Concentration (EBC) model which is derived from the Ideal Adsorption Solution Theory (IAST) provided the best correlation with the experimental data in natural waters. The concentrations of competing NOM and inorganic ions estimated by the EBC model were <10% of their initial concentrations. Sulphates are the most competitive inorganic ions followed by nitrates and bicarbonates and the multicomponent interactions could be well predicted by using the IAST-EBC model. However, the EBC model failed in the presence of higher molecular weight Suwannee River Humic Acid (SRHA) molecules due to neglecting of the pore blocking phenomenon. In the presence of higher molecular weight SRHA molecules, the Redlich-Peterson Isotherm (RP) model exhibited a better performance than the Sheindorf–Rebuhn–Sheintuch (SRS) and the EBC models.
图文摘要:

12799. 题目: Tillage frequency affects microbial metabolic activity and short-term changes in CO 2 fluxes within 1 week in karst ecosystems
文章编号: N19072414
期刊: Journal of Soils and Sediments
作者: Dan Xiao, Yingying Ye, Shuangshuang Xiao, Wei Zhang, Xunyang He, Na Liu, Zhihong Xu, Kelin Wang
更新时间: 2019-07-24
摘要: Purpose: Tillage disturbance can significantly affect soil microbial metabolic activity and CO2 fluxes. Nevertheless, the influence of different tillage frequencies on microbial metabolic activity and short-term temporal changes of CO2 fluxes remains unclear. Materials and methods: We established an in situ experiment with the following treatments: no tillage (T0), semiannual tillage (T1), tillage every 4 months (T2), bimonthly tillage (T3), and monthly tillage (T4). The microbial metabolic activity (Biolog EcoPlate), short-term (hours to days) temporal changes in CO2 fluxes within 1 week, and soil properties were measured after 1 year of treatment. Results and discussion: The highest CO2 emissions occurred in the first 72 h after tillage treatment and were significantly higher in T3 and T4 than in T0, T1, and T2 within 1 week. Average well color development (AWCD) values reflect microbial metabolic activity and were significantly higher in the tillage treatments (T1, T2, T3, and T4) than under no tillage. There was no significant difference in the Shannon diversity index under all treatments. A higher Simpson diversity index was observed under high tillage frequency in T2, T3, and T4 compared with T0 and T1, while the highest was observed in T2. The highest utilization of carboxylic acids, amino acids, and polymers occurred in T3 and T4 soils, whereas T2 had the highest utilization of carbohydrates, amines, and miscellaneous carbon sources. AWCD values and short-term CO2 fluxes were significantly correlated with annual changes in soil organic carbon (△SOC), annual changes in dissolved organic carbon (△DOC), microbial biomass carbon (MBC), and large macroaggregates (> 1 mm). Conclusions: These results suggest that frequent tillage disturbance increases microbial metabolic activity, which can stimulate short-term CO2 emissions through changes in soil aggregates, SOC, DOC, and MBC.

12800. 题目: Split N and P addition decreases straw mineralization and the priming effect of a paddy soil: a 100-day incubation experiment
文章编号: N19072413
期刊: Biology and Fertility of Soils
作者: Dongdong Wang, Zhenke Zhu, Muhammad Shahbaz, Liang Chen, Shoulong Liu, Kazuyuki Inubushi, Jinshui Wu, Tida Ge
更新时间: 2019-07-24
摘要: The effect of mineral fertilization and its application pattern on microbial activity and the subsequent CO2 and CH4 emissions arising from soil organic matter (SOM) or added substrate remains unclear. We quantified the decomposition of 13C-labeled straw and the priming effect (PE) governed by the N and P fertilizer application pattern during a 100-day experiment in a flooded soil. Straw addition increased the total CO2 and CH4 emissions. Straw mineralization increased by 30% and decreased by 19% after full and split NP application, respectively, compared with only straw addition. However, application of NP fertilization (full or split) inhibited straw-derived CH4 emissions compared with only straw addition. SOM decomposition was increased by straw addition, yielding a positive PE for CO2 emission. The application of split NP fertilization along with straw addition improved microbial activity, yielding the highest positive PE for CO2 emission. In contrast, compared with the control (no addition), split NP application decreased the positive PE for CH4 emission. Therefore, the straw-C-derived total CO2 equivalent emission was decreased by split NP application. These results were mainly attributable to the increased Olsen P, microbial biomass, enzyme activity, and straw-derived C microbial use efficiency of split NP application, which negatively affected the PE for CH4 emission; this was supported by the results of standardized total effects determined from structural equation models. Overall, compared with full application, split NP fertilizer application significantly decreased the straw-C mineralization rate and PE for CH4 emission, thereby mitigating greenhouse gas emission and SOM storage in paddy soil.

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